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An ylide (/ ˈ ɪ l aɪ d /) [1] or ylid (/ ˈ ɪ l ɪ d /) is a neutral dipolar molecule containing a formally negatively charged atom (usually a carbanion) directly attached to a heteroatom with a formal positive charge (usually nitrogen, phosphorus or sulfur), and in which both atoms have full octets of electrons.
"Radicals" is a song written, produced, and performed by American rapper Tyler, the Creator, and features as the third song from his debut studio album Goblin. The song sparked controversy due to its lyrical themes, and it would receive even more controversy after a student attending the University of South Alabama wrote the lyrics to the ...
Pyridinium refers to the cation [C 5 H 5 NH] +. It is the conjugate acid of pyridine. Many related cations are known involving substituted pyridines, e.g. picolines ...
Pyridine N-oxide is five orders of magnitude less basic than pyridine: the pK a of protonated pyridine-N-oxide is 0.8. [7] Protonated derivatives are isolable, e.g., [C 5 H 5 NOH]Cl. [3]
The Kröhnke pyridine synthesis is reaction in organic synthesis between α-pyridinium methyl ketone salts and α, β-unsaturated carbonyl compounds used to generate highly functionalized pyridines. Pyridines occur widely in natural and synthetic products, so there is wide interest in routes for their synthesis.
Road to the Riches is the debut album by hip hop duo Kool G Rap & DJ Polo, which was released in 1989 on then-prominent hip hop label Cold Chillin' Records.The album is notable for being one of the blueprints for the mafioso rap trend with the title track "Road to the Riches," which received strong rotation on the TV show Yo!
"Bad to the Bone" is the third single from American hip hop duo Kool G Rap & DJ Polo's 1990 album Wanted: Dead or Alive. It was later included on the compilation albums The Best of Cold Chillin (2000), Greatest Hits (2002) and Street Stories: The Best of Kool G Rap & DJ Polo (2013).
UK drill is a subgenre of drill music and road rap that originated in the South London district of Brixton from 2012 onwards. [1] [2] [3] While being sonically distinct from Chicago drill music, [4] it embraces its aesthetic and melds it with road rap, a British style of gangsta rap that became popular in the years prior to the existence of drill.