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In electrochemistry, the electrochemical potential of electrons (or any other species) is the total potential, including both the (internal, nonelectrical) chemical potential and the electric potential, and is by definition constant across a device in equilibrium, whereas the chemical potential of electrons is equal to the electrochemical ...
In thermodynamics, the chemical potential of a species is the energy that can be absorbed or released due to a change of the particle number of the given species, e.g. in a chemical reaction or phase transition.
In fact, the quantity called voltage as measured in an electronic circuit has a simple relationship to the chemical potential for electrons (Fermi level). When the leads of a voltmeter are attached to two points in a circuit, the displayed voltage is a measure of the total work transferred when a unit charge is allowed to move from one point to ...
In a battery, an electrochemical potential arising from the movement of ions balances the reaction energy of the electrodes. The maximum voltage that a battery reaction can produce is sometimes called the standard electrochemical potential of that reaction.
All species, including the electron, are at the same temperature, and appropriate standard states for all species, including the electron, must be fully defined. The absolute electrode potential is then defined as the Gibbs free energy for the absolute electrode process. To express this in volts one divides the Gibbs free energy by the negative ...
When a voltmeter is used to measure an electronic device, it does not quite measure the pure electric potential (also called Galvani potential).Instead, it measures the electrochemical potential, also called "fermi level difference", which is the total free energy difference per electron, including not only its electric potential energy but also all other forces and influences on the electron ...
Chemical bonds between atoms were explained by Gilbert Newton Lewis, who in 1916 proposed that a covalent bond between two atoms is maintained by a pair of electrons shared between them. [53] Later, in 1927, Walter Heitler and Fritz London gave the full explanation of the electron-pair formation and chemical bonding in terms of quantum ...
Galvani potential , Volta potential and surface potential in one phase. The corresponding potential differences computed between two phases. In electrochemistry, the Galvani potential (also called Galvani potential difference, or inner potential difference, Δφ, delta phi) is the electric potential difference between two points in the bulk of two phases. [1]