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Despite the foregoing, there is a difference between the two quantities. The information entropy Η can be calculated for any probability distribution (if the "message" is taken to be that the event i which had probability p i occurred, out of the space of the events possible), while the thermodynamic entropy S refers to thermodynamic probabilities p i specifically.
The concept of information entropy was introduced by Claude Shannon in his 1948 paper "A Mathematical Theory of Communication", [2] [3] and is also referred to as Shannon entropy. Shannon's theory defines a data communication system composed of three elements: a source of data, a communication channel, and a receiver. The "fundamental problem ...
Chemical reactions cause changes in entropy and system entropy, in conjunction with enthalpy, plays an important role in determining in which direction a chemical reaction spontaneously proceeds. One dictionary definition of entropy is that it is "a measure of thermal energy per unit temperature that is not available for useful work" in a ...
(Here, I(x) is the self-information, which is the entropy contribution of an individual message, and is the expected value.) A property of entropy is that it is maximized when all the messages in the message space are equiprobable p(x) = 1/n; i.e., most unpredictable, in which case H(X) = log n.
When measuring entropy using the natural logarithm (ln), the unit of information entropy is called a "nat", but when it is measured using the base-2 logarithm, the unit of information entropy is called a "shannon" (alternatively, "bit"). This is just a difference in units, much like the difference between inches and centimeters.
Entropy of a Bernoulli trial (in shannons) as a function of binary outcome probability, called the binary entropy function.. In information theory, the binary entropy function, denoted or (), is defined as the entropy of a Bernoulli process (i.i.d. binary variable) with probability of one of two values, and is given by the formula:
Although, in both cases, mutual information expresses the number of bits of information common to the two sources in question, the analogy does not imply identical properties; for example, differential entropy may be negative. The differential analogies of entropy, joint entropy, conditional entropy, and mutual information are defined as follows:
The shannon also serves as a unit of the information entropy of an event, which is defined as the expected value of the information content of the event (i.e., the probability-weighted average of the information content of all potential events). Given a number of possible outcomes, unlike information content, the entropy has an upper bound ...