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where is the ratio of the rate of the substituted reaction compared to the reference reaction, ρ* is the sensitivity factor for the reaction to polar effects, σ* is the polar substituent constant that describes the field and inductive effects of the substituent, δ is the sensitivity factor for the reaction to steric effects, and E s is ...
The power factor in a single-phase circuit (or balanced three-phase circuit) can be measured with the wattmeter-ammeter-voltmeter method, where the power in watts is divided by the product of measured voltage and current. The power factor of a balanced polyphase circuit is the same as that of any phase. The power factor of an unbalanced ...
Angle notation can easily describe leading and lagging current: . [1] In this equation, the value of theta is the important factor for leading and lagging current. As mentioned in the introduction above, leading or lagging current represents a time shift between the current and voltage sine curves, which is represented by the angle by which the curve is ahead or behind of where it would be ...
In organic chemistry, steric effects are nearly universal and affect the rates and activation energies of most chemical reactions to varying degrees. In biochemistry, steric effects are often exploited in naturally occurring molecules such as enzymes , where the catalytic site may be buried within a large protein structure.
In chemistry, Le Chatelier's principle (pronounced UK: / l ə ʃ æ ˈ t ɛ l j eɪ / or US: / ˈ ʃ ɑː t əl j eɪ /) [1] is a principle used to predict the effect of a change in conditions on chemical equilibrium. [2] Other names include Chatelier's principle, Braun–Le Chatelier principle, Le Chatelier–Braun principle or the equilibrium ...
The effect of the sigma electron displacement towards the more electronegative atom by which one end becomes positively charged and the other end negatively charged is known as the inductive effect. The -I effect is a permanent effect & generally represented by an arrow on the bond. [citation needed]
An electric effect influences the structure, reactivity, or properties of a molecule but is neither a traditional bond nor a steric effect. [1] In organic chemistry, the term stereoelectronic effect is also used to emphasize the relation between the electronic structure and the geometry (stereochemistry) of a molecule. The term polar effect is ...
In atomic physics, hyperfine structure is defined by small shifts in otherwise degenerate electronic energy levels and the resulting splittings in those electronic energy levels of atoms, molecules, and ions, due to electromagnetic multipole interaction between the nucleus and electron clouds.