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This is illustrated in the vapor pressure chart (see right) that shows graphs of the vapor pressures versus temperatures for a variety of liquids. [7] At the normal boiling point of a liquid, the vapor pressure is equal to the standard atmospheric pressure defined as 1 atmosphere, [ 1 ] 760 Torr, 101.325 kPa, or 14.69595 psi.
Reid vapor pressure (RVP) is a common measure of the volatility of gasoline and other petroleum products. [1] It is defined as the absolute vapor pressure exerted by the vapor of the liquid and any dissolved gases/moisture at 37.8 °C (100 °F) as determined by the test method ASTM-D-323, which was first developed in 1930 [2] and has been revised several times (the latest version is ASTM D323 ...
National Physical Laboratory, Kaye and Laby Tables of Physical and Chemical Constants; Section 3.4.4, D. Ambrose, Vapour pressures from 0.2 to 101.325 kPa.
The phase diagram shows, in pressure–temperature space, the lines of equilibrium or phase boundaries between the three phases of solid, liquid, and gas. The curves on the phase diagram show the points where the free energy (and other derived properties) becomes non-analytic: their derivatives with respect to the coordinates (temperature and ...
The Clausius–Clapeyron relation describes a Phase transition in a closed system composed of two contiguous phases, condensed matter and ideal gas, of a single substance, in mutual thermodynamic equilibrium, at constant temperature and pressure. Therefore, [8]: 508. Using the appropriate Maxwell relation gives [8]: 508 where is the pressure.
In thermodynamics and chemical engineering, the vapor–liquid equilibrium (VLE) describes the distribution of a chemical species between the vapor phase and a liquid phase. The concentration of a vapor in contact with its liquid, especially at equilibrium, is often expressed in terms of vapor pressure, which will be a partial pressure (a part ...
Antoine equation. The Antoine equation is a class of semi-empirical correlations describing the relation between vapor pressure and temperature for pure substances. The Antoine equation is derived from the Clausius–Clapeyron relation. The equation was presented in 1888 by the French engineer Louis Charles Antoine [fr] (1825–1897).
In thermodynamics, a critical point (or critical state) is the end point of a phase equilibrium curve. One example is the liquid–vapor critical point, the end point of the pressure–temperature curve that designates conditions under which a liquid and its vapor can coexist. At higher temperatures, the gas comes into a supercritical phase ...