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Walsh diagrams in conjunction with molecular orbital theory can also be used as a tool to predict reactivity. By generating a Walsh Diagram and then determining the HOMO/LUMO of that molecule, it can be determined how the molecule is likely to react. In the following example, the Lewis acidity of AH 3 molecules such as BH 3 and CH 3 + is predicted.
A Markov process is called a reversible Markov process or reversible Markov chain if there exists a positive stationary distribution π that satisfies the detailed balance equations [13] =, where P ij is the Markov transition probability from state i to state j, i.e. P ij = P(X t = j | X t − 1 = i), and π i and π j are the equilibrium probabilities of being in states i and j, respectively ...
Reaction coordinate diagrams also give information about the equilibrium between a reactant or a product and an intermediate. If the barrier energy for going from intermediate to product is much higher than the one for reactant to intermediate transition, it can be safely concluded that a complete equilibrium is established between the reactant ...
The system of Walsh functions is known as the Walsh system. It is an extension of the Rademacher system of orthogonal functions. [2] Walsh functions, the Walsh system, the Walsh series, [3] and the fast Walsh–Hadamard transform are all named after the American mathematician Joseph L. Walsh.
An ICE table or RICE box or RICE chart is a tabular system of keeping track of changing concentrations in an equilibrium reaction. ICE stands for initial, change, equilibrium. It is used in chemistry to keep track of the changes in amount of substance of the reactants and also organize a set of conditions that one wants to solve with. [1]
Partial equilibrium, the equilibrium price and quantity which come from the cross of supply and demand in a competitive market; Radner equilibrium, an economic concept defined by economist Roy Radner in the context of general equilibrium; Recursive competitive equilibrium, an economic equilibrium concept associated with a dynamic program
A judge in Brazil has ordered Adele’s song Million Years Ago to be removed globally from streaming services due to a plagiarism claim by Brazilian composer, Toninho Geraes. Geraes alleges that ...
The discontinuity in , and other properties, e.g. internal energy, , and entropy,, of the substance, is called a first order phase transition. [12] [13] In order to specify the unique experimentally observed pressure, (), at which it occurs another thermodynamic condition is required, for from Fig.1 it could clearly occur for any pressure in the range .