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In crystallography, crystal structure is a description of ordered arrangement of atoms, ions, or molecules in a crystalline material. [1] Ordered structures occur from intrinsic nature of constituent particles to form symmetric patterns that repeat along the principal directions of three-dimensional space in matter.
Some chemistry textbooks [3] as well as the widely used CRC Handbook of Chemistry and Physics [4] define lattice energy with the opposite sign, i.e. as the energy required to convert the crystal into infinitely separated gaseous ions in vacuum, an endothermic process. Following this convention, the lattice energy of NaCl would be +786 kJ/mol.
A lattice in the sense of a 3-dimensional array of regularly spaced points coinciding with e.g. the atom or molecule positions in a crystal, or more generally, the orbit of a group action under translational symmetry, is a translation of the translation lattice: a coset, which need not contain the origin, and therefore need not be a lattice in ...
The Morse potential has been applied to studies of molecular vibrations and solids, [22] and also inspired the functional form of more accurate potentials such as the bond-order potentials. Ionic materials are often described by a sum of a short-range repulsive term, such as the Buckingham pair potential , and a long-range Coulomb potential ...
A relatively complemented lattice is a lattice. (def) 19. A heyting algebra is distributive. [5] 20. A totally ordered set is a distributive lattice. 21. A metric lattice is modular. [6] 22. A modular lattice is semi-modular. [7] 23. A projective lattice is modular. [8] 24. A projective lattice is geometric. (def) 25. A geometric lattice is ...
Thus, the phonon dispersion relation is determined by matrices M and D, which depend on the atomic structure and the strength of interaction among constituent atoms (the stronger the interaction and the lighter the atoms, the higher is the phonon frequency and the larger is the slope dω p /dκ p).
When the oppositely charged ions in the solid ionic lattice are surrounded by the opposite pole of a polar molecule, the solid ions are pulled out of the lattice and into the liquid. If the solvation energy exceeds the lattice energy , the negative net enthalpy change of solution provides a thermodynamic drive to remove ions from their ...
In mathematical physics, a lattice model is a mathematical model of a physical system that is defined on a lattice, as opposed to a continuum, such as the continuum of space or spacetime. Lattice models originally occurred in the context of condensed matter physics, where the atoms of a crystal automatically form a lattice.