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In the NO − 3 anion, the oxidation state of the central nitrogen atom is V (+5). This corresponds to the highest possible oxidation number of nitrogen. Nitrate is a potentially powerful oxidizer as evidenced by its explosive behaviour at high temperature when it is detonated in ammonium nitrate (NH 4 NO 3), or black powder, ignited by the shock wave of a primary explosive.
Due to relatively weak N–O bonding, all nitrogen oxides are unstable with respect to N 2 and O 2, which is the principle behind the catalytic converter, and prevents the oxygen and nitrogen in the atmosphere from combusting.
A nitrate nitrite, or nitrite nitrate, is a coordination complex or other chemical compound that contains both nitrite (NO − 2) and nitrate (NO − 3) anions.They are mixed-anion compounds, and they are mixed-valence compounds.
NO 3 − + 2 H + + 2 e − → NO 2 − + H 2 O (Nitrate reductase) NO 2 − + 2 H + + e − → NO + H 2 O (Nitrite reductase) 2 NO + 2 H + + 2 e − → N 2 O + H 2 O (Nitric-oxide reductase) N 2 O + 2 H + + 2 e − → N 2 + H 2 O (Nitrous-oxide reductase) The complete process can be expressed as a net balanced redox reaction, where nitrate ...
H 2 N 2 O 2 + 2 H + + 2 e − ⇌ N 2 + 2 H 2 O; E 0 = +2.65 V. Oxidation reactions usually result in the formation of the nitrate ion, with nitrogen in oxidation state +5. For example, oxidation with permanganate ion can be used for quantitative analysis of nitrite (by titration): 5 NO − 2 + 2 MnO − 4 + 6 H + → 5 NO − 3 + 2 Mn 2+ + 3 H 2 O
A mnemonic is a memory aid used to improve long-term memory and make the process of consolidation easier. Many chemistry aspects, rules, names of compounds, sequences of elements, their reactivity, etc., can be easily and efficiently memorized with the help of mnemonics.
Nitric oxide (nitrogen oxide or nitrogen monoxide [1]) is a colorless gas with the formula NO.It is one of the principal oxides of nitrogen.Nitric oxide is a free radical: it has an unpaired electron, which is sometimes denoted by a dot in its chemical formula (• N=O or • NO).
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