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The gas constant R is defined as the Avogadro constant N A multiplied by the Boltzmann constant k (or k B): = = 6.022 140 76 × 10 23 mol −1 × 1.380 649 × 10 −23 J⋅K −1 = 8.314 462 618 153 24 J⋅K −1 ⋅mol −1. Since the 2019 revision of the SI, both N A and k are defined with exact numerical values when expressed in SI units. [2]
The construction industry makes use of measures such as the R-value (resistance) and the U-value (transmittance or conductance). Although related to the thermal conductivity of a material used in an insulation product or assembly, R- and U-values are measured per unit area, and depend on the specified thickness of the product or assembly. [note 2]
The R-value is the building industry term [3] for thermal resistance "per unit area." [4] It is sometimes denoted RSI-value if the SI units are used. [5] An R-value can be given for a material (e.g., for polyethylene foam), or for an assembly of materials (e.g., a wall or a window). In the case of materials, it is often expressed in terms of R ...
Although Boltzmann first linked entropy and probability in 1877, the relation was never expressed with a specific constant until Max Planck first introduced k, and gave a more precise value for it (1.346 × 10 −23 J/K, about 2.5% lower than today's figure), in his derivation of the law of black-body radiation in 1900–1901. [11]
Architects and engineers call the resulting values either the U-Value or the R-Value of a construction assembly like a wall. Each type of value (R or U) are related as the inverse of each other such that R-Value = 1/U-Value and both are more fully understood through the concept of an overall heat transfer coefficient described in lower section ...
From this plot, − Δ r H / R is the slope, and Δ r S / R is the intercept of the linear fit. By measuring the equilibrium constant, K eq, at different temperatures, the Van 't Hoff plot can be used to assess a reaction when temperature changes.
To calculate thermal transmittance when there are "bridging" mortar joints it is necessary to calculate two quantities, known as R max and R min. R max can be thought of as the total thermal insulance obtained if it is assumed that there is no lateral flow of heat and R min can be thought of as the total thermal insulance obtained if it is ...
R is the ideal gas constant. M is the molar mass of the solvent. T b is boiling point of the pure solvent in kelvin. ΔH vap is the molar enthalpy of vaporization of the solvent. Through the procedure called ebullioscopy, a known constant can be used to calculate an unknown molar mass. The term ebullioscopy means "boiling measurement" in Latin.