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This notation is used to specify electron configurations and to create the term symbol for the electron states in a multi-electron atom. When writing a term symbol, the above scheme for a single electron's orbital quantum number is applied to the total orbital angular momentum associated to an electron state. [4]
For atoms, the notation consists of a sequence of atomic subshell labels (e.g. for phosphorus the sequence 1s, 2s, 2p, 3s, 3p) with the number of electrons assigned to each subshell placed as a superscript. For example, hydrogen has one electron in the s-orbital of the first shell, so its configuration is written 1s 1.
Orbital position vector, orbital velocity vector, other orbital elements. In astrodynamics and celestial dynamics, the orbital state vectors (sometimes state vectors) of an orbit are Cartesian vectors of position and velocity that together with their time () uniquely determine the trajectory of the orbiting body in space.
A two-line element set (TLE, or more rarely 2LE) or three-line element set (3LE) is a data format encoding a list of orbital elements of an Earth-orbiting object for a given point in time, the epoch. Using a suitable prediction formula, the state (position and velocity) at any point in the past or future can be estimated to some accuracy.
This notation means that the corresponding Slater determinants have a clear higher weight in the configuration interaction expansion. The atomic orbital concept is therefore a key concept for visualizing the excitation process associated with a given transition. For example, one can say for a given transition that it corresponds to the ...
For instance, the lone pairs of water are usually treated as two equivalent sp x hybrid orbitals, while the corresponding "nonbonding" orbitals of carbenes are generally treated as a filled σ(out) orbital and an unfilled pure p orbital, even though the lone pairs of water could be described analogously by filled σ(out) and p orbitals (for ...
In atomic physics, hyperfine structure is defined by small shifts in otherwise degenerate electronic energy levels and the resulting splittings in those electronic energy levels of atoms, molecules, and ions, due to electromagnetic multipole interaction between the nucleus and electron clouds.
Any possible choice of parts will yield a valid interaction picture; but in order for the interaction picture to be useful in simplifying the analysis of a problem, the parts will typically be chosen so that H 0,S is well understood and exactly solvable, while H 1,S contains some harder-to-analyze perturbation to this system.