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Nickel nitrate is the inorganic compound Ni(NO 3) 2 or any hydrate thereof. In the hexahydrate, the nitrate anions are not bonded to nickel. Other hydrates have also been reported: Ni(NO 3) 2. 9H 2 O, Ni(NO 3) 2. 4H 2 O, and Ni(NO 3) 2. 2H 2 O. [3] It is prepared by the reaction of nickel oxide with nitric acid: NiO + 2 HNO 3 + 5 H 2 O → Ni ...
Nickel compounds are chemical compounds containing the element nickel which is a member of the group 10 of the periodic table. Most compounds in the group have an oxidation state of +2. Nickel is classified as a transition metal with nickel(II) having much chemical behaviour in common with iron(II) and cobalt(II).
The standard Gibbs free energy of formation (G f °) of a compound is the change of Gibbs free energy that accompanies the formation of 1 mole of a substance in its standard state from its constituent elements in their standard states (the most stable form of the element at 1 bar of pressure and the specified temperature, usually 298.15 K or 25 °C).
The nickel organic acid salts are organic acid salts of nickel. In many of these the ionised organic acid acts as a ligand. Nickel acetate has the formula (CH 3 COO) 2 Ni·4H 2 O. It has monodentate acetate and hydrogen bonding. A dihydrate also exists. Nickel acetate is used to seal anodised aluminium. [1]
Dichlorobis(triphenylphosphine)nickel(II) refers to a pair of metal phosphine complexes with the formula NiCl 2 [P(C 6 H 5) 3] 2. The compound exists as two isomers, a paramagnetic dark blue solid and a diamagnetic red solid. These complexes function as catalysts for organic synthesis. [1]
Nickel forms double salts with Tutton's salt structure with tetrafluoroberyllate with the range of cations of ammonia, [4] potassium, rubidium, cesium, [5] and thallium. [6] Anhydrous salts of the formula M 2 Ni 2 (SO 4) 3, which can be termed metal nickel trisulfates, belong to the family of langbeinites.
Nickel nitrate commonly crystallises with six water molecules, [1] but can also be anhydrous, or with two, four or nine waters. [11] triphenylphosphine oxide nickel nitrate [(C 6 H 6) 3 PO] 2 Ni(NO 3) 2 is non ionic, with nitrato as a ligand. It can be made from nickel perchlorate. It is yellow and melts at 266 °C. [12]
Being the conjugate base of a strong acid (nitric acid, pK a = -1.4), nitrate has modest Lewis basicity.Two coordination modes are common: unidentate and bidentate.Often, bidentate nitrate, denoted κ 2-NO 3, is bound unsymmetrically in the sense that one M-O distance is clearly bonding and the other is more weakly interacting. [2]