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The reaction begins with the excitation of a pair of chlorophyll molecules similar to those in the bacterial reaction center. Due to the presence of chlorophyll a, as opposed to bacteriochlorophyll, Photosystem II absorbs light at a shorter wavelength. The pair of chlorophyll molecules at the reaction center are often referred to as P680. [1]
The underlying force driving these reactions is the Gibbs free energy of the reactants relative to the products. If donor and acceptor (the reactants) are of higher free energy than the reaction products, the electron transfer may occur spontaneously. The Gibbs free energy is the energy available ("free") to do work.
The following is a breakdown of the energetics of the photosynthesis process from Photosynthesis by Hall and Rao: [6]. Starting with the solar spectrum falling on a leaf, 47% lost due to photons outside the 400–700 nm active range (chlorophyll uses photons between 400 and 700 nm, extracting the energy of one 700 nm photon from each one)
Besides chlorophyll, plants also use pigments such as carotenes and xanthophylls. [25] Algae also use chlorophyll, but various other pigments are present, such as phycocyanin, carotenes, and xanthophylls in green algae, phycoerythrin in red algae (rhodophytes) and fucoxanthin in brown algae and diatoms resulting in a wide variety of colors.
Chlorophyll b is a form of chlorophyll. Chlorophyll b helps in photosynthesis by absorbing light energy. It is more soluble than chlorophyll a in polar solvents because of its carbonyl group. Its color is green, and it primarily absorbs blue light. [2] In land plants, the light-harvesting antennae around photosystem II contain the majority of ...
Cyanobacteria is the only prokaryotic group that performs oxygenic photosynthesis. Anoxygenic photosynthetic bacteria use PSI- and PSII-like photosystems, which are pigment protein complexes for capturing light. [5] Both of these photosystems use bacteriochlorophyll. There are multiple hypotheses for how oxygenic photosynthesis evolved.
The reaction center is made of two chlorophyll molecules and is therefore referred to as a dimer. [11] The dimer is thought to be composed of one chlorophyll a molecule and one chlorophyll a′ molecule. However, if P700 forms a complex with other antenna molecules, it can no longer be a dimer. [13]
In years 1950–1953 in particular, chlorophyll was used as a marketing tool to promote toothpaste, sanitary towels, soap and other products. This was based on claims that it was an odor blocker — a finding from research by F. Howard Westcott in the 1940s — and the commercial value of this attribute in advertising led to many companies ...