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The structure of the solid indicates a close association of the NH and the BH centers. The closest H−H distance is 1.990 Å, which can be compared with the H−H bonding distance of 0.74 Å. This interaction is called a dihydrogen bond. [10] [11] The original crystallographic analysis of this compound reversed the assignments of B and N.
Lewis structures – also called Lewis dot formulas, Lewis dot structures, electron dot structures, or Lewis electron dot structures (LEDs) – are diagrams that show the bonding between atoms of a molecule, as well as the lone pairs of electrons that may exist in the molecule. [1][2][3] A Lewis structure can be drawn for any covalently bonded ...
Left: The dot-and-cross diagram of the LDQ structure of ozone (O 3). The nuclei are as indicated and the electrons are denoted by either dots or crosses, depending on their relative spins. Right: Simplified diagram of the LDQ structure of O 3, showing electrons in non-coincident pairs using thin lines and a coincident electron pair using a ...
Boron trifluoride is a versatile Lewis acid that forms adducts with such Lewis bases as fluoride and ethers: CsF + BF3 → Cs [BF4] O (CH 2 CH 3) 2 + BF3 → BF3·O (CH2CH3)2. Tetrafluoroborate salts are commonly employed as non-coordinating anions.
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An unusually stable oxonium species is the gold complex tris[triphenylphosphinegold(I)]oxonium tetrafluoroborate, [(Ph 3 PAu) 3 O][BF 4], where the intramolecular aurophilic interactions between the gold atoms are believed responsible for the stabilisation of the cation.
The human disease sickle cell anemia is caused by a genetic mutation in the codon for the sixth amino acid of the blood protein beta-hemoglobin.The normal DNA sequence G-A-G codes for the amino acid glutamate, while the mutation changes the middle adenine to a thymine, leading to the sequence G-T-G (G-U-G in the mRNA).
Pourbaix diagram of iron. [1] The Y axis corresponds to voltage potential. In electrochemistry, and more generally in solution chemistry, a Pourbaix diagram, also known as a potential/pH diagram, E H –pH diagram or a pE/pH diagram, is a plot of possible thermodynamically stable phases (i.e., at chemical equilibrium) of an aqueous electrochemical system.