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Diethyl azodicarboxylate, conventionally abbreviated as DEAD and sometimes as DEADCAT, [6] [7] is an organic compound with the structural formula CH 3 CH 2 −O−C(=O)−N=N−C(=O)−O−CH 2 CH 3. Its molecular structure consists of a central azo functional group , RN=NR, flanked by two ethyl ester groups.
The container dissipates heat more slowly in a higher-temperature environment, so at some critical temperature heat is generated by polymerization faster than the container can dissipate it and the reaction self-accelerates. Thus such a mixture has a SADT that depends on container size exactly as in the case of a pure organic peroxide.
The first limb is an isochoric adiabatic work process increasing the system's internal energy; the second, an isochoric and workless heat transfer returning the system to its original state. Accordingly, Rankine measured quantity of heat in units of work, rather than as a calorimetric quantity. [18]
Also acid ionization constant or acidity constant. A quantitative measure of the strength of an acid in solution expressed as an equilibrium constant for a chemical dissociation reaction in the context of acid-base reactions. It is often given as its base-10 cologarithm, p K a. acid–base extraction A chemical reaction in which chemical species are separated from other acids and bases. acid ...
The stability of a chemical compound is eventually limited when exposed to extreme environmental conditions such as heat, radiation, humidity, or the acidity of a solvent. Because of this chemical decomposition is often an undesired chemical reaction. However chemical decomposition can be desired, such as in various waste treatment processes.
Therefore, the heat of the reaction is a direct measure of the free energy change, =. In solution chemistry, on the other hand, most chemical reactions are kept at constant pressure. Under this condition, the heat of the reaction is equal to the enthalpy change of the system.
In electrochemistry, the Nernst equation is a chemical thermodynamical relationship that permits the calculation of the reduction potential of a reaction (half-cell or full cell reaction) from the standard electrode potential, absolute temperature, the number of electrons involved in the redox reaction, and activities (often approximated by concentrations) of the chemical species undergoing ...
The measured heat energy released in an exothermic reaction is converted to ΔH⚬ in Joule per mole (formerly cal/mol). The standard enthalpy change Δ H ⚬ is essentially the enthalpy change when the stoichiometric coefficients in the reaction are considered as the amounts of reactants and products (in mole); usually, the initial and final ...