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Free radical reactions are redox reactions that occur as part of homeostasis and killing microorganisms. In these reactions, an electron detaches from a molecule and then re-attaches almost instantly. Free radicals are part of redox molecules and can become harmful to the human body if they do not reattach to the redox molecule or an antioxidant.
The values below are standard apparent reduction potentials (E°') for electro-biochemical half-reactions measured at 25 °C, 1 atmosphere and a pH of 7 in aqueous solution. [ 1 ] [ 2 ] The actual physiological potential depends on the ratio of the reduced ( Red ) and oxidized ( Ox ) forms according to the Nernst equation and the thermal voltage .
In electrochemistry, the Nernst equation is a chemical thermodynamical relationship that permits the calculation of the reduction potential of a reaction (half-cell or full cell reaction) from the standard electrode potential, absolute temperature, the number of electrons involved in the redox reaction, and activities (often approximated by concentrations) of the chemical species undergoing ...
For oxidation-reduction reactions in acidic conditions, after balancing the atoms and oxidation numbers, one will need to add H + ions to balance the hydrogen ions in the half reaction. For oxidation-reduction reactions in basic conditions, after balancing the atoms and oxidation numbers, first treat it as an acidic solution and then add OH − ...
Illustration of a redox reaction Sodium chloride is formed through the redox reaction of sodium metal and chlorine gas. Redox reactions can be understood in terms of the transfer of electrons from one involved species (reducing agent) to another (oxidizing agent). In this process, the former species is oxidized and the latter is reduced. Though ...
The chain of redox reactions driving the flow of electrons through the electron transport chain, from electron donors such as NADH to electron acceptors such as oxygen and hydrogen (protons), is an exergonic process – it releases energy, whereas the synthesis of ATP is an endergonic process, which requires an input of energy.
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