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Sodium sulfate is a typical electrostatically bonded ionic sulfate. The existence of free sulfate ions in solution is indicated by the easy formation of insoluble sulfates when these solutions are treated with Ba 2+ or Pb 2+ salts: Na 2 SO 4 + BaCl 2 → 2 NaCl + BaSO 4. Sodium sulfate is unreactive toward most oxidizing or reducing agents.
His production of sodium sulfate, which he called sal mirabilis or "wonderful salt", brought him fame and the honor of being named "Glauber's salt". It was an effective but relatively safe laxative at a time when purging (emptying the digestive tract) was a popular treatment for many diseases.
Collected salt mounds Naturally formed salt crystals Ancient method of boiling brine into pure salt in China. Salt, also referred to as table salt or by its chemical formula NaCl (sodium chloride), is an ionic compound made of sodium and chloride ions. All life depends on its chemical properties to survive.
Sodium salts of long chain sulfonic acids (e.g. sodium lauryl sulfate) are often included in toothpaste and shampoo. The sodium salts of fatty acids may serve as soaps and can therefore be called sodium soaps.
The vitriol salts, from the Latin vitreolum, glassy, were so-called because they were some of the first transparent crystals known. [8] Green vitriol is iron(II) sulfate heptahydrate, FeSO 4 ·7H 2 O; blue vitriol is copper(II) sulfate pentahydrate, CuSO 4 ·5H 2 O and white vitriol is zinc sulfate heptahydrate, ZnSO 4 ·7H 2 O.
In the first step, sodium chloride is treated with sulfuric acid in the Mannheim process. This reaction produces sodium sulfate (called the salt cake) and hydrogen chloride: 2 NaCl + H 2 SO 4 → Na 2 SO 4 + 2 HCl. This chemical reaction had been discovered in 1772 by the Swedish chemist Carl Wilhelm Scheele.
Salts have long had a wide variety of uses and applications. Many minerals are ionic. [82] Humans have processed common salt (sodium chloride) for over 8000 years, using it first as a food seasoning and preservative, and now also in manufacturing, agriculture, water conditioning, for de-icing roads, and many other uses. [83]
An example of this crystallization process is the production of Glauber's salt, a crystalline form of sodium sulfate. In the diagram, where equilibrium temperature is on the x-axis and equilibrium concentration (as mass percent of solute in saturated solution) in y-axis , it is clear that sulfate solubility quickly decreases below 32.5 °C.
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