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Crystal growth is achieved by the further addition of folded polymer chain segments and only occurs for temperatures below the melting temperature T m and above the glass transition temperature T g. Higher temperatures destroy the molecular arrangement and below the glass transition temperature, the movement of molecular chains is frozen. [ 6 ]
Some polymer solutions also have a lower critical solution temperature (LCST) or lower bound to a temperature range of partial miscibility. As shown in the diagram, for polymer solutions the LCST is higher than the UCST, so that there is a temperature interval of complete miscibility, with partial miscibility at both higher and lower temperatures.
This is not a set temperature and is dependent upon factors including the following: [3] Increasing annealing time decreases recrystallization temperature; Alloys have higher recrystallization temperatures than pure metals; Increasing amount of cold work decreases recrystallization temperature
Crystallization is the process by which solids form, where the atoms or molecules are highly organized into a structure known as a crystal. Some ways by which crystals form are precipitating from a solution , freezing , or more rarely deposition directly from a gas .
However, semicrystalline polymers (B) undergo crystallization and melting (at temperatures T c and T m, respectively). DSC is used widely for examining polymeric materials to determine their thermal transitions. Important thermal transitions include the glass transition temperature (T g), crystallization temperature (T c), and melting ...
The monomers are polymerized by heating for a few days. Contrary to the light-initiated topochemical polymerization, the lower temperature and slower reaction rate would produce high quality polymer crystals. This is due to the fact that heat expansion is not obvious in lower temperature. [23]
Crystal growth is a major stage of a crystallization process, and consists of the addition of new atoms, ions, or polymer strings into the characteristic arrangement of the crystalline lattice. [ 1 ] [ 2 ] The growth typically follows an initial stage of either homogeneous or heterogeneous (surface catalyzed) nucleation , unless a "seed ...
The annealing temperature is selected to promote the full crystallization and avoiding the formation of detrimental secondary phases, pores, and cracks. Various temperatures are reported in different literature sources; however, crystallization does not usually start below 550-600 °C, while temperatures larger than 850 °C cause the extensive ...