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This page contains tables of azeotrope data for various binary and ternary mixtures of solvents. The data include the composition of a mixture by weight (in binary azeotropes, when only one fraction is given, it is the fraction of the second component), the boiling point (b.p.) of a component, the boiling point of a mixture, and the specific gravity of the mixture.
1.344 at 20.0 °C [1] ... Gas properties Std enthalpy change ... Vapor-liquid Equilibrium for Acetonitrile/Methanol [4] P = 760 mmHg BP Temp.
The following table lists the Van der Waals constants (from the Van der Waals equation) for a number of common gases and volatile liquids. [ 1 ] To convert from L 2 b a r / m o l 2 {\displaystyle \mathrm {L^{2}bar/mol^{2}} } to L 2 k P a / m o l 2 {\displaystyle \mathrm {L^{2}kPa/mol^{2}} } , multiply by 100.
Gas properties Std enthalpy change of formation, Δ f H o gas: −218.5 kJ/mol Standard molar entropy, S o gas: 295.35 J/(mol K) Heat capacity, c p: 75 J/(mol K) van der Waals' constants [3] a = 1409.4 L 2 kPa/mol 2 b = 0.0994 liter per mole
Polar aprotic solvents: acetone: C 3 H 6 O 56.05 °C 21.83 0.7845 g/cm 3: 2.91 reacts with strong acids and bases acetonitrile : CH 3 CN 81.3 - 82.1 °C 38.3 0.776 g/cm 3: 3.20 reacts with strong acids and bases dichloromethane: CH 2 Cl 2: 39.6 °C 9.08 1.3266 g/cm 3: 1.6 low boiling point dimethylformamide (CH 3) 2 NCHO 153 °C 36.7 0.95 g/cm ...
1.328 at 20 °C ... 79.9 J/(mol K) at 20 °C Gas properties Std enthalpy change of formation, ... Methanol vapor pressure vs. temperature.
Acetonitrile has only modest toxicity in small doses. [11] [19] It can be metabolised to produce hydrogen cyanide, which is the source of the observed toxic effects. [9] [20] [21] Generally the onset of toxic effects is delayed, due to the time required for the body to metabolize acetonitrile to cyanide (generally about 2–12 hours). [11]
In reversed phase chromatography, the most polar compounds elute first with the more nonpolar compounds eluting later. The mobile phase is generally a mixture of water and miscible polarity-modifying organic solvent, such as methanol, acetonitrile or THF. Retention increases as the fraction of the polar solvent (water) in the mobile phase is ...