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In aqueous solution, ammonia deprotonates a small fraction of the water to give ammonium and hydroxide according to the following equilibrium: . NH 3 + H 2 O ⇌ NH + 4 + OH −.. In a 1 M ammonia solution, about 0.42% of the ammonia is converted to ammonium, equivalent to pH = 11.63 because [NH +
Ammonia forms 1:1 adducts with a variety of Lewis acids such as I 2, phenol, and Al(CH 3) 3. Ammonia is a hard base (HSAB theory) and its E & C parameters are E B = 2.31 and C B = 2.04. Its relative donor strength toward a series of acids, versus other Lewis bases, can be illustrated by C-B plots .
[1] To convert from L 2 b a r / m o l 2 {\displaystyle \mathrm {L^{2}bar/mol^{2}} } to L 2 k P a / m o l 2 {\displaystyle \mathrm {L^{2}kPa/mol^{2}} } , multiply by 100. To convert from L 2 b a r / m o l 2 {\displaystyle \mathrm {L^{2}bar/mol^{2}} } to m 6 P a / m o l 2 {\displaystyle \mathrm {m^{6}Pa/mol^{2}} } , divide by 10.
Substance Formula 0 °C 10 °C 20 °C 30 °C 40 °C 50 °C 60 °C 70 °C 80 °C 90 °C 100 °C Barium acetate: Ba(C 2 H 3 O 2) 2: 58.8: 62: 72: 75: 78.5: 77: 75
Pourbaix diagram of iron. [1] The Y axis corresponds to voltage potential. In electrochemistry, and more generally in solution chemistry, a Pourbaix diagram, also known as a potential/pH diagram, E H –pH diagram or a pE/pH diagram, is a plot of possible thermodynamically stable phases (i.e., at chemical equilibrium) of an aqueous electrochemical system.
0.58816 g/cm 3: 1.0431×10 −2 g/cm 3: 1124 J/g 40 °C: 1554 kPa 0.57948 g/cm 3: 1.2006×10 −2 g/cm 3: 1101 J/g 45 °C: 1781 kPa 0.57130 g/cm 3: 1.3775×10 −2 g/cm 3: 1083 J/g 50 °C: 2032 kPa 0.56287 g/cm 3: 1.5761×10 −2 g/cm 3: 1052 J/g 55 °C: 2310 kPa 0.55420 g/cm 3 60 °C: 2613 kPa 0.54523 g/cm 3: 2.05×10 −2 g/cm 3 65 °C: 2947 ...
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A strong acid, such as hydrochloric acid, at concentration 1 mol dm −3 has a pH of 0, while a strong alkali like sodium hydroxide, at the same concentration, has a pH of 14. Since pH is a logarithmic scale, a difference of one in pH is equivalent to a tenfold difference in hydrogen ion concentration.