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Robert Wilhelm Eberhard Bunsen (German:; 30 March 1811 [a] – 16 August 1899) was a German chemist.He investigated emission spectra of heated elements, and discovered caesium (in 1860) and rubidium (in 1861) with the physicist Gustav Kirchhoff. [11]
This laid way for spectrochemical analysis in laboratory and astrophysical science. Bunsen and Kirchhoff applied the optical techniques of Fraunhofer, Bunsen's improved flame source and a highly systematic experimental procedure to a detailed examination of the spectra of chemical compounds. They established the linkage between chemical ...
In 1860, the unexpected appearance of sky-blue and dark red was observed in spectral emissions by Robert Bunsen and Gustav Kirchhoff, leading to the discovery of two alkali metals, caesium and rubidium (dark red). [4] [1] Today, this low-cost method is used in secondary education to teach students to detect metals in samples qualitatively. [2]
Robert Bunsen and Gustav Kirchhoff were the first to establish atomic emission spectroscopy as a tool in chemistry. [1] When an element is burned in a flame, its atoms move from the ground electronic state to the excited electronic state. As atoms in the excited state move back down into the ground state, they emit light.
Gustav Robert Kirchhoff (German: [ˈgʊs.taf ˈkɪʁçhɔf]; 12 March 1824 – 17 October 1887) was a German physicist, mathematican and chemist who contributed to the fundamental understanding of electrical circuits, spectroscopy and the emission of black-body radiation by heated objects.
The first instrumental analysis was flame emissive spectrometry developed by Robert Bunsen and Gustav Kirchhoff who discovered rubidium (Rb) and caesium (Cs) in 1860. [4] Most of the major developments in analytical chemistry took place after 1900. During this period, instrumental analysis became progressively dominant in the field.
It is the least electronegative element with stable isotopes, of which it has only one, caesium-133. Caesium is mined mostly from pollucite, while the radioisotopes, especially caesium-137, are extracted from waste produced by nuclear reactors. German chemists Robert Bunsen and Gustav Kirchhoff discovered caesium in 1860 by flame spectroscopy.
They discovered caesium by its two blue emission lines in a sample of Dürkheim mineral water. [130] The pure metal was eventually isolated in 1882 by Setterberg. [131] 37 Rubidium: 1861 R. Bunsen and G. R. Kirchhoff: 1863 R. Bunsen Bunsen and Kirchhoff discovered it just a few months after caesium, by observing new spectral lines in the ...