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Robert Wilhelm Eberhard Bunsen (German:; 30 March 1811 [a] – 16 August 1899) was a German chemist. He investigated emission spectra of heated elements, and discovered caesium (in 1860) and rubidium (in 1861) with the physicist Gustav Kirchhoff. [11] The Bunsen–Kirchhoff Award for spectroscopy is named after Bunsen and Kirchhoff.
This laid way for spectrochemical analysis in laboratory and astrophysical science. Bunsen and Kirchhoff applied the optical techniques of Fraunhofer, Bunsen's improved flame source and a highly systematic experimental procedure to a detailed examination of the spectra of chemical compounds. They established the linkage between chemical ...
In 1860, the unexpected appearance of sky-blue and dark red was observed in spectral emissions by Robert Bunsen and Gustav Kirchhoff, leading to the discovery of two alkali metals, caesium and rubidium (dark red). [4] [1] Today, this low-cost method is used in secondary education to teach students to detect metals in samples qualitatively. [2]
Gustav Robert Kirchhoff (German: [ˈgʊs.taf ˈkɪʁçhɔf]; 12 March 1824 – 17 October 1887) was a German physicist, mathematican and chemist who contributed to the fundamental understanding of electrical circuits, spectroscopy and the emission of black-body radiation by heated objects.
They discovered caesium by its two blue emission lines in a sample of Dürkheim mineral water. [130] The pure metal was eventually isolated in 1882 by Setterberg. [131] 37 Rubidium: 1861 R. Bunsen and G. R. Kirchhoff: 1863 R. Bunsen Bunsen and Kirchhoff discovered it just a few months after caesium, by observing new spectral lines in the ...
1860–61: Discovery of caesium and rubidium by Robert Bunsen and Gustav Kirchhoff [139] 1860: Erlenmeyer flask by Emil Erlenmeyer [ 140 ] 1863–64: Discovery of indium by Ferdinand Reich and Hieronymous Theodor Richter [ 141 ] [ 142 ] [ 143 ]
This is carried out by measuring the Zeeman effect on specific hyperfine structure transition levels of the source element (cesium) and applying a uniformly precise, low-strength magnetic field to said source, in a process known as degaussing. [13] The Zeeman effect may also be utilized to improve accuracy in atomic absorption spectroscopy.
With Robert Bunsen (1811–1899) he developed flame spectroscopy in 1859, which can be used to detect chemical elements with high specificity. [27] Bunsen was a chemist from Göttingen, he discovered together with Kirchhoff the elements caesium and rubidium in 1861.