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  2. tert-Butanesulfinamide - Wikipedia

    en.wikipedia.org/wiki/Tert-Butanesulfinamide

    tert-Butanesulfinamide (also known as 2-methyl-2-propanesulfinamide or Ellman's sulfinamide) is an organosulfur compound and a member of the class of sulfinamides. Both enantiomeric forms are commercially available and are used in asymmetric synthesis as chiral auxiliaries, often as chiral ammonia equivalents for the synthesis of amines.

  3. tert-Butyl bromide - Wikipedia

    en.wikipedia.org/wiki/Tert-butyl_bromide

    tert-Butyl bromide (also referred to as 2-bromo-2-methylpropane) is an organic compound with the formula Me 3 CBr (Me = methyl). The molecule features a tert-butyl group attached to a bromide substituent. This organobromine compound is used as a standard reagent in synthetic organic chemistry. It is a colorless liquid.

  4. Comparison of psychoactive alcohols in alcoholic drinks

    en.wikipedia.org/wiki/Comparison_of_psychoactive...

    0.9% (mean) in Rye mash cistern room: 534–1197 mg/100 mL 2460 mg/kg 2-Methylbutan-2-ol: None (tertiary alcohol) 0.07% in beer: 70 mg/100 mL (see tert-Pentyl alcohol in ref) Found in cassava fermented drinks: 1000 mg/kg 2-Methylpropan-2-ol None (tertiary alcohol) Identified, not quantified, in beer [5] 2743 mg/kg 2-Phenylethan-1-ol ? 0.1% in ...

  5. Di-tert-butyl ether - Wikipedia

    en.wikipedia.org/wiki/Di-tert-butyl_ether

    2-tert-Butoxy-2-methylpropane Di-tert-butyl ether. Identifiers CAS Number. ... 0.7658 g/cm 3 [2] Melting point: −61 °C (−78 °F; 212 K) [4] Boiling point:

  6. Butyl group - Wikipedia

    en.wikipedia.org/wiki/Butyl_group

    The effect of the tert-butyl group on the progress of a chemical reaction is called the Thorpe–Ingold effect illustrated in the Diels-Alder reaction below. Compared to a hydrogen substituent, the tert-butyl substituent accelerates the reaction rate by a factor of 240. [2] tert-Butyl effect. The tert-butyl effect is an example of steric hindrance.

  7. tert-Butyl alcohol - Wikipedia

    en.wikipedia.org/wiki/Tert-Butyl_alcohol

    tert-Butyl alcohol is used as a solvent, ethanol denaturant, paint remover ingredient, and gasoline octane booster and oxygenate.It is a chemical intermediate used to produce methyl tert-butyl ether (MTBE) and ethyl tert-butyl ether (ETBE) by reaction with methanol and ethanol, respectively, and tert-butyl hydroperoxide (TBHP) by reaction with hydrogen peroxide.

  8. Di-tert-butyl peroxide - Wikipedia

    en.wikipedia.org/wiki/Di-tert-butyl_peroxide

    For this reason di-tert-butyl peroxide is commonly used as a radical initiator in organic synthesis and polymer chemistry. The decomposition reaction proceeds via the generation of methyl radicals. (CH 3) 3 COOC(CH 3) 3 → 2 (CH 3) 3 CO • (CH 3) 3 CO • → (CH 3) 2 CO + CH • 3 2 CH • 3 → C 2 H 6

  9. Methyl tert-butyl ether - Wikipedia

    en.wikipedia.org/wiki/Methyl_tert-butyl_ether

    Methyl tert-butyl ether (MTBE), also known as tert-butyl methyl ether, is an organic compound with a structural formula (CH 3) 3 COCH 3. MTBE is a volatile, flammable, and colorless liquid that is sparingly soluble in water. [ 1 ]