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Formyl functional group is shown in blue. Formylation refers to any chemical processes in which a compound is functionalized with a formyl group (-CH=O). In organic chemistry, the term is most commonly used with regards to aromatic compounds (for example the conversion of benzene to benzaldehyde in the Gattermann–Koch reaction).
Aldehyde structure. In organic chemistry, an aldehyde (/ ˈ æ l d ɪ h aɪ d /) is an organic compound containing a functional group with the structure R−CH=O. [1] The functional group itself (without the "R" side chain) can be referred to as an aldehyde but can also be classified as a formyl group.
Ferrocenecarboxaldehyde, owing to the versatility of the formyl group, is a precursor to many ferrocene-modified compounds. With a Wittig reagent, it converts to vinylferrocene and related derivatives. [5] With primary amines, ferrocenecarboxaldehyde condenses to give imines. The azomethine derivative undergoes 1,3-cycloaddition to C 60. [6]
Formic acid is a source for a formyl group for example in the formylation of N-methylaniline to N-methylformanilide in toluene. [20] In synthetic organic chemistry, formic acid is often used as a source of hydride ion, as in the Eschweiler–Clarke reaction: The Eschweiler–Clark reaction
N-Formylmethionine (fMet, [2] HCO-Met, [3] For-Met [3]) is a derivative of the amino acid methionine in which a formyl group has been added to the amino group. It is specifically used for initiation of protein synthesis from bacterial and organellar genes, and may be removed post-translationally.
In chemistry a formylation reaction is a class of addition reaction, in which a formyl group is added to a substituent to give an aldehyde. Pages in category "Formylation reactions" The following 8 pages are in this category, out of 8 total.
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If the carbon in the carbonyl group cannot be included in the attached chain (for instance in the case of cyclic aldehydes), the prefix "formyl-" or the suffix "-carbaldehyde" is used: C 6 H 11 CHO is cyclohexanecarbaldehyde. If an aldehyde is attached to a benzene and is the main functional group, the suffix becomes benzaldehyde.