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Black oxide or blackening is a conversion coating for ferrous materials, stainless steel, copper and copper based alloys, zinc, powdered metals, and silver solder. [1] It is used to add mild corrosion resistance, for appearance, and to minimize light reflection. [ 2 ]
Various processes are used to produce the oxide coating. "Cold" bluing is generally a selenium dioxide-based compound that colours steel black, or more often a very dark grey. It is a difficult product to apply evenly, offers minimal protection and is generally best used for small fast repair jobs and touch-ups.
Phosphate conversion coating is a chemical treatment applied to steel parts that creates a thin adhering layer of iron, zinc, or manganese phosphates to improve corrosion resistance or lubrication or as a foundation for subsequent coatings or painting. [1] [2] [3] It is one of the most common types of conversion coating.
A conversion coating is a chemical or electro-chemical treatment applied to manufactured parts that superficially converts the material into a thin adhering coating of an insoluble compound. These coatings are commonly applied to protect the part against corrosion , to improve the adherence of other coatings, for lubrication , or for aesthetic ...
Tannic acid chemically converts the reddish iron oxides into bluish-black ferric tannate, a more stable material. [2] The second active ingredient is an organic solvent such as 2-butoxyethanol (ethylene glycol monobutyl ether, trade name butyl cellosolve) that acts as a wetting agent and provides a protective primer layer in conjunction with an ...
Coatings of moderate thickness 1.8 μm to 25 μm (0.00007" to 0.001") [16] are known as Type II in North America, as named by MIL-A-8625, while coatings thicker than 25 μm (0.001") are known as Type III, hard-coat, hard anodizing, or engineered anodizing. Very thin coatings similar to those produced by chromic anodizing are known as Type IIB.
An additional step can be added to the nitrocarburizing process called post-oxidation. When properly performed, post-oxidation creates a layer of black oxide (Fe 3 O 4), that greatly increases the corrosion resistance of the treated substrate while leaving an aesthetically attractive black color. [25]
Mill scale is a complex oxide that contains around 70% iron with traces of nonferrous metals and alkaline compounds. Reduced iron powder may be obtained by conversion of mill scale into a single highest oxide i.e. hematite (Fe 2 O 3) followed by reduction with hydrogen.
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