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In chemistry the negative of the decimal logarithm, the decimal cologarithm, is indicated by the letter p. [63] For instance, pH is the decimal cologarithm of the activity of hydronium ions (the form hydrogen ions H + take in water). [64] The activity of hydronium ions in neutral water is 10 −7 mol·L −1, hence a pH of 7. Vinegar typically ...
Logarithms can be used to make calculations easier. For example, two numbers can be multiplied just by using a logarithm table and adding. These are often known as logarithmic properties, which are documented in the table below. [2] The first three operations below assume that x = b c and/or y = b d, so that log b (x) = c and log b (y) = d.
The logarithm keys (log for base-10 and ln for base-e) on a typical scientific calculator. The advent of hand-held calculators largely eliminated the use of common logarithms as an aid to computation. The numerical value for logarithm to the base 10 can be calculated with the following identities: [5]
The natural logarithm can be defined for any positive real number a as the area under the curve y = 1/x from 1 to a [4] (with the area being negative when 0 < a < 1). The simplicity of this definition, which is matched in many other formulas involving the natural logarithm, leads to the term "natural".
The distribution coefficient, log D, is the ratio of the sum of the concentrations of all forms of the compound (ionized plus un-ionized) in each of the two phases, one essentially always aqueous; as such, it depends on the pH of the aqueous phase, and log D = log P for non-ionizable compounds at any pH.
Since the common logarithm of a power of 10 is exactly the exponent, the characteristic is an integer number, which makes the common logarithm exceptionally useful in dealing with decimal numbers. For positive numbers less than 1, the characteristic makes the resulting logarithm negative, as required. [38]
The positive part and negative part of a function are used to define the Lebesgue integral for a real-valued function. Analogously to this decomposition of a function, one may decompose a signed measure into positive and negative parts — see the Hahn decomposition theorem.
Like Log P, Log D is positive for lipophilic and negative for hydrophilic substances. While P values are largely independent of the pH value of the aqueous phase due to their restriction to only one species, D values are often strongly dependent on the pH value of the aqueous phase.