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The gold number is the minimum weight (in milligrams) of a protective colloid/lyophilic colloid required to prevent the coagulation of 10 ml of a standard hydro gold sol when 1 ml of a 10% sodium chloride solution is added to it. [1] It was first used by Richard Adolf Zsigmondy in 1901.
When lyophilic sols are added to lyophobic sols, depending on their sizes, either lyophobic sol is adsorbed in the surface of lyophilic sol or lyophilic sol is adsorbed on the surface of lyophobic sol. The layer of the protective colloid prevents direct collision between the hydrophobic colloidal particles and thus prevents coagulation. [1]
In 1923, Peter Debye and Erich Hückel reported the first successful theory for the distribution of charges in ionic solutions. [7] The framework of linearized Debye–Hückel theory subsequently was applied to colloidal dispersions by S. Levine and G. P. Dube [8] [9] who found that charged colloidal particles should experience a strong medium-range repulsion and a weaker long-range attraction.
The table describes varying contact angles and their corresponding solid/liquid and liquid/liquid interactions. [9] For nonwater liquids, the term lyophilic is used for low contact angle conditions and lyophobic is used when higher contact angles result. Similarly, the terms omniphobic and omniphilic apply to both polar and apolar liquids.
A sol is a colloidal suspension made out of tiny solid particles [1] in a continuous liquid medium. Sols are stable, so that they do not settle down when left undisturbed, and exhibit the Tyndall effect, which is the scattering of light by the particles in the colloid.
The table below summarizes the critical coagulation concentration (CCC) ranges for different net charge of the counter ion. [4] The charge is expressed in units of elementary charge . This dependence reflects the Schulze–Hardy rule, [ 5 ] [ 6 ] which states that the CCC varies as the inverse sixth power of the counter ion charge.
The depletion force is an effect of increased osmotic pressure in the surrounding solution. When colloids get sufficiently close, that is when their excluded volumes overlap, depletants are expelled from the interparticle region. This region between colloids then becomes a phase of pure solvent. When this occurs, there is a higher depletant ...
Unlike solutions and colloids, if left undisturbed for a prolonged period of time, the suspended particles will settle out of the mixture. Although suspensions are relatively simple to distinguish from solutions and colloids, it may be difficult to distinguish solutions from colloids since the particles dispersed in the medium may be too small ...