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In organic chemistry, an acetal is a functional group with the connectivity R 2 C(OR') 2. Here, the R groups can be organic fragments (a carbon atom, with arbitrary other atoms attached to that) or hydrogen, while the R' groups must be organic fragments not hydrogen. The two R' groups can be equivalent to each other (a "symmetric acetal") or ...
In IUPAC nomenclature, an acetyl group is called an ethanoyl group. An acetyl group contains a methyl group (−CH 3) that is single-bonded to a carbonyl (C=O), making it an acyl group. The carbonyl center of an acyl radical has one non-bonded electron with which it forms a chemical bond to the remainder (denoted with the letter R) of the molecule.
Acetyl-CoA then enters the citric acid cycle, where the acetyl group is oxidized to carbon dioxide and water, and the energy released is captured in the form of 11 ATP and one GTP per acetyl group. Konrad Bloch and Feodor Lynen were awarded the 1964 Nobel Prize in Physiology or Medicine for their discoveries linking acetyl-CoA and fatty acid ...
The reactivity of a functional group can be modified by other functional groups nearby. Functional group interconversion can be used in retrosynthetic analysis to plan organic synthesis. A functional group is a group of atoms in a molecule with distinctive chemical properties, regardless of the other atoms in the molecule.
Acid catalyzed acetal formation from the corresponding hemiacetal. Acetals, as already pointed out, are stable tetrahedral intermediates so they can be used as protective groups in organic synthesis. Acetals are stable under basic conditions, so they can be used to protect ketones from a base. The acetal group is hydrolyzed under acidic conditions.
The process involves the chemical reaction of acetic anhydride with the free hydroxyl groups in wood polymers, mostly of lignin and hemicelluloses, without requiring a catalyst. The modification results in bonds between the structural polymeric components, significantly reducing the ability of the -OH groups to form hydrogen bonds with water ...
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A spiro compound, or spirane, from the Latin spīra, meaning a twist or coil, [22] [5]: 1138 [23] is a chemical compound, typically an organic compound, that presents a twisted structure of two or more rings (a ring system), in which 2 or 3 rings are linked together by one common atom, [2]: SP-0