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Electroless nickel-boron plating developed as a variant of the similar nickel-phosphorus process, discovered accidentally by Charles Adolphe Wurtz in 1844. [2]In 1969, Harold Edward Bellis from DuPont filed a patent for a general class of electroless plating processes using sodium borohydride, dimethylamine borane, or sodium hypophosphite, in the presence of thallium salts, thus producing a ...
Nickel superalloy jet engine turbine blade. A superalloy, or high-performance alloy, is an alloy with the ability to operate at a high fraction of its melting point. [1] Key characteristics of a superalloy include mechanical strength, thermal creep deformation resistance, surface stability, and corrosion and oxidation resistance.
In this process boron atoms are diffused into the surface of a metal component. The resulting surface contains metal borides , such as iron borides, nickel borides, and cobalt borides, As pure materials, these borides have extremely high hardness and wear resistance.
Electroless nickel plating uses nickel salts as the metal cation source and either hypophosphite (H 2 PO 2-) (or a borohydride-like compound) as a reducer. [6] A side reaction forms elemental phosphorus (or boron) which is incorporated in the coating. The classical deposition methods follows the following steps:
Electroless processes are widely used to deposit nickel-phosphorus or nickel-boron alloys for wear and corrosion resistance, silver for mirror-making, copper for printed circuit boards, and many more. A major advantage of these processes over electroplating is that they can produce coatings of uniform thickness over surfaces of arbitrary shape ...
Electroless nickel-phosphorus coatings with less than 7% phosphorus are solid solutions with a microcrystalline structure, with each grain 2–6 nm across. Coatings with more than 10% phosphorus are amorphous. Between these two limits, the coating is a mixture of amorphous and microcrystalline materials. [16]
WASHINGTON (Reuters) -The U.S. government posted a $367 billion budget deficit for November, up 17% from a year earlier, as calendar adjustments for benefit payments boosted outlays by some $80 ...
Nickel boride is the common name of materials composed chiefly of the elements nickel and boron that are widely used as catalysts in organic chemistry. [1] [2] Their approximate chemical composition is Ni 2.5 B, [3] and they are often incorrectly denoted "Ni 2 B" in organic chemistry publications.
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