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[11] [12] Bent's rule states "[A]tomic s character concentrates in orbitals directed toward electropositive substituents". [2] Bent's rule implies that bond angles will deviate from the bond angle predicted by VSEPR theory; the relative electronegativities of atoms surrounding the central atom will impact the molecule geometry. [5]
Another example is O(SiH 3) 2 with an Si–O–Si angle of 144.1°, which compares to the angles in Cl 2 O (110.9°), (CH 3) 2 O (111.7°), and N(CH 3) 3 (110.9°). [24] Gillespie and Robinson rationalize the Si–O–Si bond angle based on the observed ability of a ligand's lone pair to most greatly repel other electron pairs when the ligand ...
This is because according to Bent's rule, the C–F bond gains p-orbital character leading to high s-character in the C–H bonds, and H–C–H bond angles approaching those of sp 2 orbitals – e.g. 120° – leaving less for the F–C–H bond angle. The difference is again explained in terms of bent bonds.
Consequently, the bond angles are set at 120°. For example, boron trifluoride. Angular: Angular molecules (also called bent or V-shaped) have a non-linear shape. For example, water (H 2 O), which has an angle of about 105°. A water molecule has two pairs of bonded electrons and two unshared lone pairs.
Water (H 2 O) is an example of a bent molecule, as well as its analogues. The bond angle between the two hydrogen atoms is approximately 104.45°. [ 1 ] Nonlinear geometry is commonly observed for other triatomic molecules and ions containing only main group elements, prominent examples being nitrogen dioxide (NO 2 ), sulfur dichloride (SCl 2 ...
However, this prediction (120° bond angles) is inconsistent with the bond angle of H 2 O being 104.5°. The actual hybridization of H 2 O can be explained via the concept of isovalent hybridization or Bent's rule. In short, s character is accumulated in lone pair orbitals because s character is energy lowering relative to p character, and lone ...
[17] [18] The familiar alkynes have a carbon-carbon triple bond (bond order 3) and a linear geometry of 180° bond angles (figure A in reference [19]). However, further down in the group (silicon, germanium, and tin), formal triple bonds have an effective bond order 2 with one lone pair (figure B [19]) and trans-bent geometries.
From memory the rule is that the odd electron (or "half electron pair") counts as a full electron pair for determining the basic shape, but takes up less space for determining the bond angle - ex. bent 134° in NO 2 vs. bent 120° (approx.) in NO 2-and 117-118° in ClO 2 vs. close to tetrahedral (109°) in ClO 2-.