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A permanganate (/ p ər ˈ m æ ŋ ɡ ə n eɪ t, p ɜːr-/) [1] is a chemical compound with the manganate(VII) ion, MnO − 4, the conjugate base of permanganic acid. Because the manganese atom has a +7 oxidation state, the permanganate(VII) ion is a strong oxidising agent. The ion is a transition metal ion with a tetrahedral structure. [2]
Alum in the form of potassium aluminium sulphate or ammonium aluminium sulfate in a concentrated bath of hot water is regularly used by jewelers and machinists to dissolve hardened steel drill bits that have broken off in items made of aluminum, copper, brass, gold (any karat), silver (both sterling and fine) and stainless steel. This is ...
Aluminium–manganese alloys (AlMn alloys) are aluminium alloys that contain manganese (Mn) as the main alloying element. They consist mainly of aluminium (Al); in addition to manganese, which accounts for the largest proportion of about 1% of the alloying elements, but they may also contain small amounts of iron (Fe), silicon (Si), magnesium (Mg), or copper (Cu).
Its reaction with the aluminium, similar to magnesium/teflon/viton thermite, adds energy to the reaction. [5] Of the listed compositions, that with potassium permanganate has the highest pressurization rate. [6] The most common method of preparing nanoenergetic materials is by ultrasonification in quantities of less than 2g.
Ammonium permanganate is a strong oxidizer, owing to its permanganate anion, and it is a moderately strong explosive, owing to the combination of oxidizer permanganate anion and reducing ammonium cation. Dry ammonium permanganate can detonate by heat, shock, or friction, and it may explode at temperatures above 140 °F (60 °C). [1]
The stoichiometric ratio is 34.2% aluminum and 65.8% perchlorate by mass. A ratio of seven parts potassium perchlorate to three parts dark pyro aluminium is the composition used by most pyrotechnicians. For best results, the aluminium powder should be "Dark Pyro" grade, with a flake particle shape, and a particle size of fewer than 10 micrometres.
The salt is prepared from the reaction of potassium permanganate with calcium chloride [2] or from the reaction of aluminium permanganate with calcium oxide.It can also be prepared by reacting manganese dioxide with a solution of calcium hypochlorite and a little bit of calcium hydroxide to increase the pH level.
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