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Buckminsterfullerene is the most common naturally occurring fullerene. Small quantities of it can be found in soot. [5] [6] It also exists in space. Neutral C 60 has been observed in planetary nebulae [7] and several types of star. [8]
The calculated data allows using C 60 fullerene as a Faraday cage, [13] which isolates the encapsulated atom from the external electric field. The mentioned relations should be typical for the more complicated endohedral structures (e.g., C 60 @C 240 [14] and giant fullerene-containing "onions" [15]).
Scheme 1 presents an overview of the first step, the creation of a 13 membered ring orifice on the fullerene surface. A 1,2,4-triazine 2 is fitted with two phenyl groups and a pyridine group for reasons of solubility and reacted in 1,2-dichlorobenzene with pristine C 60 fullerene 2 in a Diels-Alder reaction at high temperature and for an extended reaction time.
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Fullerene chemistry is a field of organic chemistry devoted to the chemical properties of fullerenes. [1] [2] [3] Research in this field is driven by the need to functionalize fullerenes and tune their properties. For example, fullerene is notoriously insoluble and adding a suitable group can enhance solubility. [1]
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