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For common optical glasses, the refractive index calculated with the three-term Sellmeier equation deviates from the actual refractive index by less than 5×10 −6 over the wavelengths' range [5] of 365 nm to 2.3 μm, which is of the order of the homogeneity of a glass sample. [6]
In a dispersive prism, material dispersion (a wavelength-dependent refractive index) causes different colors to refract at different angles, splitting white light into a spectrum. A compact fluorescent lamp seen through an Amici prism. Dispersion is the phenomenon in which the phase velocity of a wave depends on its frequency. [1]
This is a result of the prism material's index of refraction varying with wavelength (dispersion). Generally, longer wavelengths (red) undergo a smaller deviation than shorter wavelengths (blue). The dispersion of white light into colors by a prism led Sir Isaac Newton to conclude that white light consisted of a mixture of different colors.
Rayleigh scattering is defined by a mathematical formula that requires the light-scattering particles to be far smaller than the wavelength of the light. [6] For a dispersion of particles to qualify for the Rayleigh formula, the particle sizes need to be below roughly 40 nanometres (for visible light), [citation needed] and the particles may be ...
For example, the higher dispersion flint glasses have relatively small Abbe numbers < whereas the lower dispersion crown glasses have larger Abbe numbers. Values of V d {\displaystyle V_{\mathsf {d}}} range from below 25 for very dense flint glasses, around 34 for polycarbonate plastics, up to 65 for common crown glasses, and 75 to 85 for some ...
Maxwell's equations are the basis of theoretical and computational methods describing light scattering, but since exact solutions to Maxwell's equations are only known for selected particle geometries (such as spherical), light scattering by particles is a branch of computational electromagnetics dealing with electromagnetic radiation ...
Circular dichroism causes incident linearly polarized light to become elliptically polarized. The two phenomena are closely related, just as are ordinary absorption and dispersion. If the entire optical rotatory dispersion spectrum is known, the circular dichroism spectrum can be calculated, and vice versa.
The name "dispersion relation" originally comes from optics. It is possible to make the effective speed of light dependent on wavelength by making light pass through a material which has a non-constant index of refraction, or by using light in a non-uniform medium such as a waveguide. In this case, the waveform will spread over time, such that ...