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Polyvinyl alcohol (PVOH, PVA, or PVAl) is a water-soluble synthetic polymer. It has the idealized formula [CH 2 CH(OH)] n. It is used in papermaking, textile warp sizing, as a thickener and emulsion stabilizer in polyvinyl acetate (PVAc) adhesive formulations, in a variety of coatings, and 3D printing. It is colourless (white) and odorless.
Polyethylene absorbs almost no water; the gas and water vapour permeability (only polar gases) is lower than for most plastics. Oxygen, carbon dioxide and flavorings, on the other hand, can pass it easily. Polyethylene burns slowly with a blue flame having a yellow tip and gives off an odour of paraffin (similar to candle flame). The material ...
Consider the example of polyethylene terephthalate (PET or "polyester"). The monomers which could be used to create this polymer are ethylene glycol and terephthalic acid: HO-CH 2-CH 2-OH and HOOC-C 6 H 4-COOH In the polymer, there are two structural units, which are -O-CH 2-CH 2-O- and -CO-C 6 H 4-CO- The repeat unit is -CH 2-CH 2-O-CO-C 6 H 4 ...
Ethylene vinyl alcohol (EVOH) is a formal copolymer of ethylene and vinyl alcohol. Because the latter monomer mainly exists as its tautomer acetaldehyde , the copolymer is prepared by polymerization of ethylene and vinyl acetate to give the ethylene vinyl acetate (EVA) copolymer followed by hydrolysis.
[17] Piping systems for the conveyance of water, chemicals or gases are commonly produced in Polypropylene, and to a much greater extent Polyethylene. Piping systems in high-density Polyethylene (HDPE, PE100, PE80) are fast becoming the most commonly used drinking water, waste water and natural gas distribution piping systems in the world.
Epoxide monomers may be cross linked with themselves, or with the addition of a co-reactant, to form epoxy; BPA is the monomer precursor for polycarbonate; Terephthalic acid is a comonomer that, with ethylene glycol, forms polyethylene terephthalate. Dimethylsilicon dichloride is a monomer that, upon hydrolysis, gives polydimethylsiloxane.
For example, polyester chains grow by reaction of alcohol and carboxylic acid groups to form ester links with loss of water. However, there are exceptions; for example polyurethanes are step-growth polymers formed from isocyanate and alcohol bifunctional monomers) without loss of water or other volatile molecules, and are classified as addition ...
The degradation of polyethylene occurs by random scission—a random breakage of the bonds that hold the atoms of the polymer together. When heated above 450 °C, polyethylene degrades to form a mixture of hydrocarbons. In the case of chain-end scission, monomers are released and this process is referred to as unzipping or depolymerization ...