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Phenylacetylene is a prototypical terminal acetylene, undergoing many reactions expected of that functional group. It undergoes semi hydrogenation over Lindlar catalyst to give styrene . In the presence of base and copper(II) salts, it undergoes oxidative coupling to give diphenylbutadiyne . [ 6 ]
The Hay coupling is variant of the Glaser coupling. It relies on the TMEDA complex of copper(I) chloride to activate the terminal alkyne. Oxygen (air) is used in the Hay variant to oxidize catalytic amounts of Cu(I) to Cu(II) throughout the reaction, as opposed to a stoichiometric amount of Cu(II) used in the Eglington variant. [7]
Chemical nomenclature, replete as it is with compounds with very complex names, is a repository for some names that may be considered unusual. A browse through the Physical Constants of Organic Compounds in the CRC Handbook of Chemistry and Physics (a fundamental resource) will reveal not just the whimsical work of chemists, but the sometimes peculiar compound names that occur as the ...
Algar–Flynn–Oyamada reaction; Alkylimino-de-oxo-bisubstitution; Alkyne trimerisation; Alkyne zipper reaction; Allan–Robinson reaction; Allylic rearrangement; Amadori rearrangement; Amine alkylation; Angeli–Rimini reaction; Andrussov oxidation; Appel reaction; Arbuzov reaction, Arbusow reaction; Arens–Van Dorp synthesis, Isler ...
Yet another method involves the coupling of iodobenzene and the copper salt of phenylacetylene in the Castro-Stephens coupling. The related Sonogashira coupling involves the coupling of iodobenzene and phenylacetylene. Diphenylacetylene is a planar molecule. The central C≡C distance is 119.8 picometers. [1]
In the English language, many animals have different names depending on whether they are male, female, young, domesticated, or in groups. The best-known source of many English words used for collective groupings of animals is The Book of Saint Albans, an essay on hunting published in 1486 and attributed to Juliana Berners. [1]
Palladium precatalyst species are activated under reaction conditions to form a reactive Pd 0 compound, A. The exact identity of the catalytic species depends strongly upon reaction conditions. With simple phosphines, such as PPh 3 (n=2), and in case of bulky phosphines (i.e., P(o-Tol) 3) it was demonstrated that monoligated species (n=1) are ...
The following is a list of tautonyms: zoological names of species consisting of two identical words (the generic name and the specific name have the same spelling). Such names are allowed in zoology, but not in botany, where the two parts of the name of a species must differ (though differences as small as one letter are permitted, as in cumin, Cuminum cyminum).