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Similarly, sodium selenide is readily oxidized to polyselenides, a conversion signaled by off-white samples. Sodium selenide reacts with acids to produce toxic hydrogen selenide gas. Na 2 Se + 2 HCl → H 2 Se + 2 NaCl. The compound reacts with electrophiles to produce the selenium compounds.
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The Shorigen reaction is also used in the generation of phenylsodium, where an alkyl sodium compound is treated with benzene: [3] RNa + C 6 H 6 → RH + C 6 H 5 Na. The method can also result in the addition of a second sodium. This dimetallation occurs in the meta and para positions. The use of certain alkyl sodium compounds such as n-amyl ...
A hydroselenide (or biselenide or selanide) is an ion or chemical compound containing the [SeH] − ion. The radical HSe is a pseudohalogen.Hydroselenide can be a ligand in transition metal complexes where it can be attached to a single atom, or bridge two atoms.
Sample of cadmium selenide, a pigment. The parent inorganic selenide is hydrogen selenide (H 2 Se). It is a colorless, malodorous, toxic gas. It dissolves in aqueous solution, to give the hydrogenselenide or biselenide ion HSe −. At higher pH, selenide forms. Solutions of hydrogen selenide and selenide are oxidized by air to give elemental ...
Sodium benzeneselenolate; Trimethylsilyl phenyl selenide; The most common oxidizing agent employed is hydrogen peroxide (H 2 O 2). [9] It is sometimes used in excess, to overcome catalytic decomposition of H 2 O 2 by selenium; however, undesired oxidation of starting material has been observed under these conditions.
Sodium hydroselenide is an inorganic compound with the chemical formula Na Se H. It is a salt of hydrogen selenide. It consist of sodium cations Na + and hydroselenide anions − SeH. Each unit consists of one sodium, one selenium, and one hydrogen atom. Sodium hydroselenide is a selenium analog of sodium hydroxide NaOH.
A reaction characteristic of Ph 2 Se 2 is its reduction: . Ph 2 Se 2 + 2 Na → 2 PhSeNa. PhSeNa is a useful nucleophile used to introduce the phenylselenyl group by nucleophilic substitution of alkyl halides, alkyl sulfonates (mesylates or tosylates) and epoxides.