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Chemisorption is a kind of adsorption which involves a chemical reaction between the surface and the adsorbate. New chemical bonds are generated at the adsorbent surface. Examples include macroscopic phenomena that can be very obvious, like corrosion [clarification needed], and subtler effects associated with heterogeneous catalysis, where the catalyst and reactants are in different pha
Adsorption is the adhesion of ions or molecules onto the surface of another phase. [1] Adsorption may occur via physisorption and chemisorption. Ions and molecules can adsorb to many types of surfaces including polymer surfaces.
The key assumption used in deriving the BET equation that the successive heats of adsorption for all layers except the first are equal to the heat of condensation of the adsorbate. The Langmuir isotherm is usually better for chemisorption, and the BET isotherm works better for physisorption for non-microporous surfaces.
Breaking the atomic bonds of the dissociating molecule requires a large amount of energy, thus dissociative adsorption is an example of chemisorption, where strong adsorbate-substrate bonds are created. [1] These bonds can be atomic, ionic or metallic in nature. In contrast to dissociative adsorption, in molecular adsorption the adsorbate stays ...
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gas molecules only interact with adjacent layers; and; the Langmuir theory can be applied to each layer. the enthalpy of adsorption for the first layer is constant and greater than the second (and higher). the enthalpy of adsorption for the second (and higher) layers is the same as the enthalpy of liquefaction. The resulting BET equation is