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Delocalizing the radical ion stabilizes the transition state structure. As a result, the energy of activation decreases, enhancing the rate of the overall reaction. According to the captodative effect, the rate of a reaction is the greatest when both the EDG and EWG are able to delocalize the radical ion in the transition state structure. [7]
An electron donating group (EDG) or electron releasing group (ERG, Z in structural formulas) is an atom or functional group that donates some of its electron density into a conjugated π system via resonance (mesomerism) or inductive effects (or induction)—called +M or +I effects, respectively—thus making the π system more nucleophilic.
CBRE Group, Inc. (an initialism of Coldwell Banker Richard Ellis) is an American commercial real estate services and investment firm. [2] It is the world's largest commercial real estate services and investment firm (based on 2022 revenue).
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The real-estate firm says the average home value rose by 2.6% annually in October. It says homebuying activity should pick up after a long slump, despite choppiness in mortgage rates. Between ...
Founded in 1914, the business and the metroplex seemed to grow together. In a 1999 editorial naming the leading 20 Dallasites of the 20th Century, Henry S. Miller was called "the master of real estate brokerage." [1] The company was founded by Henry S. Miller, Sr., who had worked in retail and real estate prior to venturing out on his own.
Peanut Butter Blossoms. As the story goes, a woman by the name of Mrs. Freda F. Smith from Ohio developed the original recipe for these for The Grand National Pillsbury Bake-Off competition in 1957.
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