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A substance is pyrophoric (from Ancient Greek: πυροφόρος, pyrophoros, 'fire-bearing') if it ignites spontaneously in air at or below 54 °C (129 °F) (for gases) or within 5 minutes after coming into contact with air (for liquids and solids). [1] Examples are organolithium compounds and triethylborane.
Category II flammable liquids are those with boiling points > 35 °C/95 °F and flash points < 23 °C/73 °F [1] [5] Category III flammable liquids are those with flash points > 23 °C/73 °F and ≤ 60 °C/140 °F [1] [5] Category IV flammable liquids are those with flash points > 60 °C/140 °F and ≤ 93 °C/199.4 °F [1] [5]
Pyrophoric liquids are liable to ignite after 5 minutes of coming in contact with air. Pyrophoric solids follow the same criteria as pyrophoric liquids. Self-heating substances, which differ from self-reactive substances in that they will only ignite in large quantities (kilograms) and after a long duration of time (hours or days).
5.1: Liquid Any material which exhibits a mean pressure rise time less than or equal to the pressure rise time of a 1:1 nitric acid (65 percent)/cellulose mixture and the criteria for Packing Group I and II are not met. Group II 5.2: All All Division 5.2 materials do not have a packing group in Column 5 of the 49 CFR 172.101 Table.
The GHS transport pictograms are the same as those recommended in the UN Recommendations on the Transport of Dangerous Goods, widely implemented in national regulations such as the U.S. Federal Hazardous Materials Transportation Act (49 U.S.C. 5101–5128) and D.O.T. regulations at 49 C.F.R. 100–185.
Extremely flammable liquid and vapour H225: Highly flammable liquid and vapour H226: Flammable liquid and vapour H227: Combustible liquid H228: Flammable solid H229: Pressurized container: may burst if heated H230: May react explosively even in the absence of air H231: May react explosively even in the absence of air at elevated pressure and/or ...
NFPA 704 safety squares on containers of ethyl alcohol and acetone. "NFPA 704: Standard System for the Identification of the Hazards of Materials for Emergency Response" is a standard maintained by the U.S.-based National Fire Protection Association.
Diethylzinc (C 2 H 5) 2 Zn, or DEZ, is a highly pyrophoric and reactive organozinc compound consisting of a zinc center bound to two ethyl groups. This colourless liquid is an important reagent in organic chemistry. It is available commercially as a solution in hexanes, heptane, or toluene, or as a pure liquid.