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This ongoing current in both directions is called the exchange current density. When the potential is set more negative than the formal potential, the cathodic current is greater than the anodic current. Written as a reduction, cathodic current is positive. The net current density is the difference between the cathodic and anodic current density.
The exchange current is the current at equilibrium, i.e. the rate at which oxidized and reduced species transfer electrons with the electrode. In other words, the exchange current density is the rate of reaction at the reversible potential (when the overpotential is zero by definition).
A current–voltage characteristic or I–V curve (current–voltage curve) is a relationship, typically represented as a chart or graph, between the electric current through a circuit, device, or material, and the corresponding voltage, or potential difference, across it.
Position vectors r and r′ used in the calculation. The starting point is Maxwell's equations in the potential formulation using the Lorenz gauge: =, = where φ(r, t) is the electric potential and A(r, t) is the magnetic vector potential, for an arbitrary source of charge density ρ(r, t) and current density J(r, t), and is the D'Alembert operator. [2]
The electric potential and the magnetic vector potential together form a four-vector, so that the two kinds of potential are mixed under Lorentz transformations. Practically, the electric potential is a continuous function in all space, because a spatial derivative of a discontinuous electric potential yields an electric field of impossibly ...
The potential density of a fluid parcel at pressure is the density that the parcel would acquire if adiabatically brought to a reference pressure , often 1 bar (100 kPa). Whereas density changes with changing pressure, potential density of a fluid parcel is conserved as the pressure experienced by the parcel changes (provided no mixing with ...
Angle notation can easily describe leading and lagging current: . [1] In this equation, the value of theta is the important factor for leading and lagging current. As mentioned in the introduction above, leading or lagging current represents a time shift between the current and voltage sine curves, which is represented by the angle by which the curve is ahead or behind of where it would be ...
The electric potential outside each material is controlled by its work function, and so dissimilar metals can show an electric potential difference even at equilibrium. The Volta potential is not an intrinsic property of the two bulk metals under consideration, but rather is determined by work function differences between the metals' surfaces ...