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Under kinetic reaction control, one or both forward reactions leading to the possible products is significantly faster than the equilibration between the products. After reaction time t, the product ratio is the ratio of rate constants k and thus a function of the difference in activation energies E a or ΔG ‡:
A high force, over a short duration, usually causes more damage to both bodies than a lower force applied over a proportionally longer duration. At normal speeds, during a perfectly inelastic collision , an object struck by a projectile will deform , and this deformation will absorb most or all of the force of the collision.
the "chemical affinity" or "reaction force" between A and B did not just depend on the chemical nature of the reactants, as had previously been supposed, but also depended on the amount of each reactant in a reaction mixture. Thus the law of mass action was first stated as follows:
The rate equation for S N 2 reactions are bimolecular being first order in Nucleophile and first order in Reagent. The determining factor when both S N 2 and S N 1 reaction mechanisms are viable is the strength of the Nucleophile. Nuclephilicity and basicity are linked and the more nucleophilic a molecule becomes the greater said nucleophile's ...
At any instant of time, the net force on a body is equal to the body's acceleration multiplied by its mass or, equivalently, the rate at which the body's momentum is changing with time. If two bodies exert forces on each other, these forces have the same magnitude but opposite directions. [1] [2]
By Newton's laws of motion, any external forces that act on a system must be balanced by internal reaction forces, [1] or cause the particles in the affected part to accelerate. In a solid object, all particles must move substantially in concert in order to maintain the object's overall shape.
c) The rate of reaction progress (product formation) is monitored over time by methods such as reaction progress calorimetry or may be obtained by taking the first derivative of (a). d) Describing the rate of reaction progress with respect to consumption of starting material spreads the data into a more informative distribution than observed in ...
Castigliano's method for calculating displacements is an application of his second theorem, which states: If the strain energy of a linearly elastic structure can be expressed as a function of generalised force Q i then the partial derivative of the strain energy with respect to generalised force gives the generalised displacement q i in the direction of Q i.