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This equation, Bragg's law, describes the condition on θ for constructive interference. [12] A map of the intensities of the scattered waves as a function of their angle is called a diffraction pattern. Strong intensities known as Bragg peaks are obtained in the diffraction pattern when the scattering angles satisfy Bragg condition.
In X-ray crystallography, wide-angle X-ray scattering (WAXS) or wide-angle X-ray diffraction (WAXD) is the analysis of Bragg peaks scattered to wide angles, which (by Bragg's law) are caused by sub-nanometer-sized structures. [1] It is an X-ray-diffraction [2] method and commonly used to determine a range of information about crystalline materials.
While the Bragg formulation assumes a unique choice of direct lattice planes and specular reflection of the incident X-rays, the Von Laue formula only assumes monochromatic light and that each scattering center acts as a source of secondary wavelets as described by the Huygens principle. Each scattered wave contributes to a new plane wave given by:
where the magnitude of the scattering vector q is in reciprocal lattice distance units, N is the number of atoms, f i (q) is the atomic scattering factor for atom i and scattering vector q, while r ij is the distance between atom i and atom j. One can also use this to predict the effect of nano-crystallite shape on detected diffraction peaks ...
When the incident light beam is at Bragg angle, a diffraction pattern emerges where an order of diffracted beam occurs at each angle θ that satisfies: [3] = Here, m = ..., −2, −1, 0, +1, +2, ... is the order of diffraction, λ is the wavelength of light in vacuum, and Λ is the wavelength of the sound. [4]
Consider the scattering of a beam of wavelength by an assembly of particles or atoms stationary at positions , =, …,.Assume that the scattering is weak, so that the amplitude of the incident beam is constant throughout the sample volume (Born approximation), and absorption, refraction and multiple scattering can be neglected (kinematic diffraction).
Scattering also includes the interaction of billiard balls on a table, the Rutherford scattering (or angle change) of alpha particles by gold nuclei, the Bragg scattering (or diffraction) of electrons and X-rays by a cluster of atoms, and the inelastic scattering of a fission fragment as it traverses a thin foil.
where G, R g, and B are constants related to the scattering contrast, structural volume, surface area, and radius of gyration. q is the magnitude of the scattering vector which is related to the Bragg spacing, d, q = 2π/d = 4π/λ sin(θ/2). λ is the wavelength and θ is the scattering angle (2θ in diffraction).