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The Eyring equation (occasionally also known as Eyring–Polanyi equation) is an equation used in chemical kinetics to describe changes in the rate of a chemical reaction against temperature. It was developed almost simultaneously in 1935 by Henry Eyring , Meredith Gwynne Evans and Michael Polanyi .
Using the Eyring equation, there is a straightforward relationship between ΔG ‡, first-order rate constants, and reaction half-life at a given temperature. At 298 K, a reaction with Δ G ‡ = 23 kcal/mol has a rate constant of k ≈ 8.4 × 10 −5 s −1 and a half life of t 1/2 ≈ 2.3 hours, figures that are often rounded to k ~ 10 −4 s ...
In 1930, Eyring proposed an equation for reverberation time known as the Eyring equation. [8] Beginning in 1945, Eyring personally supervised the planning [9] and construction of a new science building at BYU. [10] When the cement was laid for the building, Eyring sprayed it with a special hose [clarification needed] to help it cure better. It ...
In chemical kinetics, the entropy of activation of a reaction is one of the two parameters (along with the enthalpy of activation) that are typically obtained from the temperature dependence of a reaction rate constant, when these data are analyzed using the Eyring equation of the transition state theory.
In 1935, with only one month difference, both Henry Eyring in Princeton, [3] and Michael Polanyi and Meredith Gwynne Evans in Manchester [4] published the founding papers on transition state theory, formulating what is now known as the "Eyring equation" which opened up a new era in the study of chemical kinetics.
The kinetic theory of gases allows accurate calculation of the temperature-variation of gaseous viscosity. The theoretical basis of the kinetic theory is given by the Boltzmann equation and Chapman–Enskog theory, which allow accurate statistical modeling of molecular trajectories.
However, Eyring's equation becomes more valid for smaller rooms with large quantities of absorption. As a result, the Eyring equation is often implemented to estimate the reverberation time in recording studio control rooms or other critical listening environments with high quantities of sound absorption. The Sabine equation tends to over ...
Henry Eyring (February 20, 1901 – December 26, 1981) was a Mexico-born United States theoretical chemist whose primary contribution was in the study of chemical reaction rates and intermediates. Eyring developed the Absolute Rate Theory or Transition state theory of chemical reactions, connecting the fields of chemistry and physics through ...