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Photoexcitation is the first step in a photochemical process where the reactant is elevated to a state of higher energy, an excited state.The first law of photochemistry, known as the Grotthuss–Draper law (for chemists Theodor Grotthuss and John W. Draper), states that light must be absorbed by a chemical substance in order for a photochemical reaction to take place.
Photodissociation, photolysis, photodecomposition, or photofragmentation is a chemical reaction in which molecules of a chemical compound are broken down by absorption of light or photons. It is defined as the interaction of one or more photons with one target molecule that dissociates into two fragments.
A 2nd order polynomial relationship between absorption and concentration is sometimes encountered [13] for very large, complex molecules such as organic dyes (xylenol orange or neutral red, for example). [14] [15] UV–Vis spectroscopy is also used in the semiconductor industry to measure the thickness and optical properties of thin films on a ...
IR spectrum showing carbonyl absorption due to UV degradation of polyethylene. Sensitive polymers include thermoplastics and speciality fibers like aramids. UV absorption leads to chain degradation and loss of strength at sensitive points in the chain structure. Aramid rope must be shielded with a sheath of thermoplastic if it is to retain its ...
To derive SUVA, first, UVC light (UV spectrum subtypes) at 254 nm or 280 nm, [2] is measured in units of absorbance per meter of path length, often the sample must be diluted with ultrapure water because absorbance can be high. [3]
IR spectrum showing carbonyl absorption due to UV degradation of polyethylene. Degradation can be detected before serious cracks are seen in a product by using infrared spectroscopy, [58] which is able to detect chemical species formed by photo-oxidation. In particular, peroxy-species and carbonyl groups have distinct absorption bands.
Ozone in the ozone layer filters out sunlight wavelengths from about 200 nm UV rays to 315 nm, with ozone peak absorption at about 250 nm. [55] This ozone UV absorption is important to life, since it extends the absorption of UV by ordinary oxygen and nitrogen in air (which absorb all wavelengths < 200 nm) through the lower UV-C (200–280 nm ...
The protection of food from photodegradation is very important. Some nutrients, for example, are affected by degradation when exposed to sunlight. In the case of beer, UV radiation causes a process that entails the degradation of hop bitter compounds to 3-methyl-2-buten-1-thiol and therefore changes the taste. As amber-colored glass has the ...