Search results
Results from the WOW.Com Content Network
For example, chlorination and bromination of naphthalene proceeds without a catalyst to give 1-chloronaphthalene and 1-bromonaphthalene, respectively. Likewise, whereas both benzene and naphthalene can be alkylated using Friedel–Crafts reaction conditions, naphthalene can also be easily alkylated by reaction with alkenes or alcohols , using ...
2-Chloronaphthalene is obtained directly by chlorination of naphthalene, with the formation of more highly substituted derivatives such as dichloro- and trichloronaphthalenes, in addition to the two monochlorinated isomeric compounds: 1-chloronaphthalene and 2-chloronaphthalene.
Sodium naphthalene is an organic salt with the chemical formula Na + [C 10 H 8] −. In the research laboratory, it is used as a reductant in the synthesis of organic, organometallic, and inorganic chemistry. It is usually generated in situ. When isolated, it invariably crystallizes as a solvate with ligands bound to Na +. [1]
Polychlorinated naphthalene (PCN) are the products obtained upon treatment of naphthalene with chlorine. The generic chemical formula is C 10 H 8−(m+n) Cl (m+n). Commercial PCNs are mixtures of up to 75 components and byproducts. [1] The material is an oil or a waxy solid, depending on the degree of chlorination.
The reagent removes pairs of H atoms from organic molecules. The stoichiometry of its action is illustrated by the conversion of tetralin to naphthalene: 2 C 6 Cl 2 (CN) 2 O 2 + C 10 H 12 → 2 C 6 Cl 2 (CN) 2 (OH) 2 + C 10 H 8. The resulting hydroquinone is poorly soluble in typical reaction solvents (dioxane, benzene, alkanes), which ...
The chlorination of the water supply helped stop the epidemic and as a precaution, the chlorination was continued until 1911 when a new water supply was commissioned. [7] Manual Control Chlorinator for the liquefaction of chlorine for water purification, early 20th century. From Chlorination of Water by Joseph Race, 1918.
The relative potency of three ring Cl-PAHs was found to increase with increasing degree of chlorination as well as with increasing degree of chlorination. However, the relative potencies of the most toxic Cl-PAHs assessed up to now have been found to be 100,000-fold lower than the relative potency of 2,3,7,8-tetrachlorodibenzo-p-dioxin (TCDD). [9]
p-DCB is produced by chlorination of benzene using ferric chloride as a catalyst: . C 6 H 6 + 2 Cl 2 → C 6 H 4 Cl 2 + 2 HCl. The chief impurity is the 1,2 isomer.The compound can be purified by fractional crystallization, taking advantage of its relatively high melting point of 53.5 °C; the isomeric dichlorobenzenes and chlorobenzene melt well below room temperature.