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First-order phase transitions exhibit a discontinuity in the first derivative of the free energy with respect to some thermodynamic variable. [6] The various solid/liquid/gas transitions are classified as first-order transitions because they involve a discontinuous change in density, which is the (inverse of the) first derivative of the free ...
The core idea behind this type of thermodynamic models is that, by constructing the fundamental property, it is possible to take advantage of thermodynamic relations that express different thermodynamic properties as the first or second-order derivatives of fundamental properties, with respect to pressure, temperature or density.
Chemical thermodynamics is the study of the interrelation of heat and work with chemical reactions or with physical changes of state within the confines of the laws of thermodynamics. Chemical thermodynamics involves not only laboratory measurements of various thermodynamic properties, but also the application of mathematical methods to the ...
Landau theory (also known as Ginzburg–Landau theory, despite the confusing name [1]) in physics is a theory that Lev Landau introduced in an attempt to formulate a general theory of continuous (i.e., second-order) phase transitions. [2]
In particular, the second-order contribution () has been calculated by Burnett. [17] In general circumstances, however, these higher-order corrections may not give reliable improvements to the first-order theory, due to the fact that the Chapman–Enskog expansion does not always converge. [ 18 ] (
The first established thermodynamic principle, which eventually became the second law of thermodynamics, was formulated by Sadi Carnot in 1824 in his book Reflections on the Motive Power of Fire. By 1860, as formalized in the works of scientists such as Rudolf Clausius and William Thomson , what are now known as the first and second laws were ...
Second derivatives of thermodynamic potentials generally describe the response of the system to small changes. The number of second derivatives which are independent of each other is relatively small, which means that most material properties can be described in terms of just a few "standard" properties.
In chemical ionization, ions are produced through the reaction of ions of a reagent gas with other species. [6] Some common reagent gases include: methane , ammonia , and isobutane . Chemi-ionization