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Dinitrogen tetroxide, commonly referred to as nitrogen tetroxide (NTO), and occasionally (usually among ex-USSR/Russian rocket engineers) as amyl, is the chemical compound N 2 O 4. It is a useful reagent in chemical synthesis. It forms an equilibrium mixture with nitrogen dioxide. Its molar mass is 92.011 g/mol.
The example of dinitrogen tetroxide (N 2 O 4) dissociating to nitrogen dioxide (NO 2) will be taken. N 2 O 4 ↽ − − ⇀ 2 NO 2 {\displaystyle {\ce {N2O4 <=> 2NO2}}} If the initial concentration of dinitrogen tetroxide is 1 mole per litre , this will decrease by α at equilibrium giving, by stoichiometry, α moles of NO 2 .
Mixed oxides of nitrogen (MON) are solutions of dinitrogen trioxide (N 2 O 3) in dinitrogen tetroxide/nitrogen dioxide (N 2 O 4 and NO 2). It may be used as an oxidizing agent in rocket propulsion systems. [1] Mixed oxides of nitrogen are produced by dissolving nitric oxide (NO) gas in liquid dinitrogen tetroxide. Nitric oxide reacts with ...
The latter two compounds are somewhat difficult to study individually because of the equilibrium between them, although sometimes dinitrogen tetroxide can react by heterolytic fission to nitrosonium and nitrate in a medium with high dielectric constant. Nitrogen dioxide is an acrid, corrosive brown gas.
It forms an equilibrium with its dimer, dinitrogen tetroxide (N 2 O 4), and converts almost entirely to N 2 O 4 below −11.2 °C (11.8 °F; 261.9 K). [ 6 ] The bond length between the nitrogen atom and the oxygen atom is 119.7 pm .
A phase diagram in physical chemistry, engineering, mineralogy, and materials science is a type of chart used to show conditions (pressure, temperature, etc.) at which thermodynamically distinct phases (such as solid, liquid or gaseous states) occur and coexist at equilibrium.
Monomethylhydrazine (MMH) is a highly toxic, volatile hydrazine derivative with the chemical formula CH 6 N 2.It is used as a rocket propellant in bipropellant rocket engines because it is hypergolic with various oxidizers such as nitrogen tetroxide (N 2 O 4) and nitric acid (HNO 3).
Ellingham diagram for several metals giving the free energy of formation of metal oxides and the corresponding oxygen partial pressure at equilibrium. Ellingham diagrams are a particular graphical form of the principle that the thermodynamic feasibility of a reaction depends on the sign of ΔG, the Gibbs free energy change, which is equal to ...