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In atomic physics and quantum chemistry, the Aufbau principle (/ ˈ aʊ f b aʊ /, from German: Aufbauprinzip, lit. ' building-up principle '), also called the Aufbau rule , states that in the ground state of an atom or ion , electrons first fill subshells of the lowest available energy , then fill subshells of higher energy.
The aufbau principle (from the German Aufbau, "building up, construction") was an important part of Bohr's original concept of electron configuration. It may be stated as: [ 13 ] a maximum of two electrons are put into orbitals in the order of increasing orbital energy: the lowest-energy subshells are filled before electrons are placed in ...
As an approximate rule, electron configurations are given by the Aufbau principle and the Madelung rule. However there are numerous exceptions; for example the lightest exception is chromium, which would be predicted to have the configuration 1s 2 2s 2 2p 6 3s 2 3p 6 3d 4 4s 2 , written as [Ar] 3d 4 4s 2 , but whose actual configuration given ...
Aufbau principle At element 118, the orbitals 1s, 2s, 2p, 3s, 3p, 3d, 4s, 4p, 4d, 4f, 5s, 5p, 5d, 5f, 6s, 6p, 6d, 7s and 7p are assumed to be filled, with the remaining orbitals unfilled. A simple extrapolation from the Aufbau principle would predict the eighth row to fill orbitals in the order 8s, 5g, 6f, 7d, 8p; but after element 120, the ...
As a result of Hund's rule, constraints are placed on the way atomic orbitals are filled in the ground state using the Aufbau principle. Before any two electrons occupy an orbital in a subshell, other orbitals in the same subshell must first each contain one electron. Also, the electrons filling a subshell will have parallel spin before the ...
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Although this is the general order of orbital filling according to the Madelung rule, there are exceptions, and the actual electronic energies of each element are also dependent upon additional details of the atoms (see Electron configuration § Atoms: Aufbau principle and Madelung rule).
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