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Polymetallic nodules, also called manganese nodules, are mineral concretions on the sea bottom formed of concentric layers of iron and manganese hydroxides around a core. As nodules can be found in vast quantities, and contain valuable metals, deposits have been identified as a potential economic interest. [ 1 ]
Pyrolusite is a mineral consisting essentially of manganese dioxide (Mn O 2) and is important as an ore of manganese. [7] It is a black, amorphous appearing mineral, often with a granular, fibrous, or columnar structure, sometimes forming reniform crusts. It has a metallic luster, a black or bluish-black streak, and readily soils the fingers.
Nodule is also used for widely scattered concretionary lumps of manganese, cobalt, iron, and nickel found on the floors of the world's oceans. This is especially true of manganese nodules. Manganese and phosphorite nodules form on the seafloor and are syndepositional in origin. Thus, technically speaking, they are concretions instead of nodules ...
Polymetallic nodules on the deep seabed in the CCZ Example of manganese nodule that can be found on the sea floor. Polymetallic nodules are found at depths of 4–6 km (2.5–3.7 mi) in all major oceans, but also in shallow waters like the Baltic Sea and in freshwater lakes. [23] [24] They are the most readily minable type of deep sea ore. [25]
Manganese is a silvery-gray metal that resembles iron. It is hard and very brittle, difficult to fuse, but easy to oxidize. [11] Manganese and its common ions are paramagnetic. [12] Manganese tarnishes slowly in air and oxidizes ("rusts") like iron in water containing dissolved oxygen. [13]
Todorokite is a rare constituent of the manganese oxide deposits at Saude and Urandi, in Bahia, Brazil, as a result of supergene enrichment of the metamorphic country rock that contains spessartine (Mn 2+ 3 Al 2 (SiO 4) 3) and other manganese minerals.
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Buserite is a hydrated layered manganese-oxide mineral with nominal chemical formula MnO 2 ·nH 2 O. It was named after Swiss chemist professor Wilhelm Buser (1917-1959), who first identified it in 1952 in deep-sea manganese nodules. Buser named it 10 Å manganate because the periodicity in the layer stacking direction was 10 Å.