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Microbiologically induced calcium carbonate precipitation (MICP) is a bio-geochemical process that induces calcium carbonate precipitation within the soil matrix. [1] Biomineralization in the form of calcium carbonate precipitation can be traced back to the Precambrian period. [ 2 ]
For example, a carboxylate may be methylated on oxygen to give a methyl ester; an alkoxide salt RO − may be likewise methylated to give an ether, ROCH 3; or a ketone enolate may be methylated on carbon to produce a new ketone. The Purdie methylation is a specific for the methylation at oxygen of carbohydrates using iodomethane and silver ...
The Fischer–Tropsch process involves a series of chemical reactions that produce a variety of hydrocarbons, ideally having the formula (C n H 2n+2). The more useful reactions produce alkanes as follows: [7] (2n + 1) H 2 + n CO → C n H 2n+2 + n H 2 O. where n is typically 10–20. The formation of methane (n = 1) is unwanted.
The C=O distance is 1.18 Å, the C−Cl distance is 1.74 Å and the Cl−C−Cl angle is 111.8°. [10] Phosgene is a carbon oxohalide and it can be considered one of the simplest acyl chlorides, being formally derived from carbonic acid .
Barbier reactions are nucleophilic addition reactions that involve relatively inexpensive, water insensitive metals (e.g zinc powder) or metal compounds. For this reason, it is possible in many cases to run the reaction in water, making the procedure part of green chemistry .
Ninhydrin exists in equilibrium with the triketone indane-1,2,3-trione, which reacts readily with nucleophiles (including water). Whereas for most carbonyl compounds, a carbonyl form is more stable than a product of water addition (hydrate), ninhydrin forms a stable hydrate of the central carbon because of the destabilizing effect of the ...
In this reaction the carbonyl group is an aldehyde or a ketone. The catalyst is usually a weakly basic amine. The active hydrogen component has the forms: [3] Z−CH 2 −Z or Z−CHR−Z for instance diethyl malonate, Meldrum's acid, ethyl acetoacetate or malonic acid, or cyanoacetic acid. [1] Z−CHRR', for instance nitromethane.
In even a slight presence of water, carbonic acid dehydrates to carbon dioxide and water, which then catalyzes further decomposition. [6] For this reason, carbon dioxide can be considered the carbonic acid anhydride. The hydration equilibrium constant at 25 °C is [H 2 CO 3]/[CO 2] ≈ 1.7×10 −3 in pure water [12] and ≈ 1.2×10 −3 in ...