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Sodium naphthalene is an organic salt with the chemical formula Na + [C 10 H 8] −. In the research laboratory, it is used as a reductant in the synthesis of organic, organometallic, and inorganic chemistry. It is usually generated in situ. When isolated, it invariably crystallizes as a solvate with ligands bound to Na +. [1]
With alkali metals, naphthalene forms the dark blue-green radical anion salts such as sodium naphthalene, Na + C 10 H − 8. The naphthalene anions are strong reducing agents. Naphthalene can be hydrogenated under high pressure in the presence of metal catalysts to give 1,2,3,4-tetrahydronaphthalene(C 10 H 12), also known as tetralin.
The fluorine-to-carbon atomic ratio (F/C ratio) is reduced from PTFE's theoretical ratio of 2.0 to 0.2 or less, after exposure to sodium naphthalene for 1 minute. [ 6 ] [ 7 ] [ 8 ] The fluorine atoms are replaced with hydroxyl, carbonyl, and other functional groups which can form hydrogen bonds.
Classical qualitative inorganic analysis is a method of analytical chemistry which seeks to find the elemental composition of inorganic compounds. It is mainly focused on detecting ions in an aqueous solution , therefore materials in other forms may need to be brought to this state before using standard methods.
The sodium fusion test, or Lassaigne's test, is used in elemental analysis for the qualitative determination of the presence of foreign elements, namely halogens, nitrogen, and sulfur, in an organic compound. It was developed by J. L. Lassaigne. [1] The test involves heating the sample with sodium metal, "fusing" it with the sample. A variety ...
Sodium atoms have 11 electrons, one more than the stable configuration of the noble gas neon. As a result, sodium usually forms ionic compounds involving the Na + cation. [1] Sodium is a reactive alkali metal and is much more stable in ionic compounds. It can also form intermetallic compounds and organosodium compounds.
Standard refractive index measurements are taken at the "yellow doublet" sodium D line, with a wavelength (λ) of 589 nanometers. There are also weaker dependencies on temperature , pressure / stress , etc., as well on precise material compositions (presence of dopants , etc.); for many materials and typical conditions, however, these ...
Thermometric titrimetry offers a rapid, highly precise method for the determination of aluminium in solution. A solution of aluminium is conditioned with acetate buffer and an excess of sodium and potassium ions. Titration with sodium or potassium fluoride yields the exothermic precipitation of an insoluble alumino-fluoride salt.